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Volumn 47, Issue 1, 2008, Pages 38-41

Heterolytic H2 activation by nonmetals

Author keywords

Carbenes; Hydrogen; Lewis acids; Lewis bases; Main group elements

Indexed keywords

ACTIVATION ANALYSIS; CHEMICAL BONDS; TRANSITION METALS;

EID: 37549038227     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200702816     Document Type: Review
Times cited : (160)

References (34)
  • 7
    • 0001526470 scopus 로고    scopus 로고
    • 2 activation by nonmetallic species that are only stable in low-temperature matrices: a Z. L. Xiao, R. H. Hauge, J. L. Margrave, Inorg. Chem. 1993, 32, 642;
    • 2 activation by nonmetallic species that are only stable in low-temperature matrices: a) Z. L. Xiao, R. H. Hauge, J. L. Margrave, Inorg. Chem. 1993, 32, 642;
  • 14
    • 24944490141 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2005, 44, 5705.
    • (2005) Chem. Int. Ed , vol.44 , pp. 5705
    • Angew1
  • 16
    • 37549022357 scopus 로고    scopus 로고
    • In the computed transition state, the H-H bond was found to be 1.071 Å, similar to those found in (η2)(H2)-metal σ complexes see Ref [2c, and longer than free H2 at 0.74 Å
    • 2 at 0.74 Å.
  • 28
  • 29
    • 37549064846 scopus 로고    scopus 로고
    • F. H. Stephens, V. Pons, R. T. Baker, Dalton Trans. 2007, 2613, and references therein.
    • b) F. H. Stephens, V. Pons, R. T. Baker, Dalton Trans. 2007, 2613, and references therein.
  • 31
    • 34447345148 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2007, 46, 4968.
    • (2007) Chem. Int. Ed , vol.46 , pp. 4968
    • Angew1
  • 33
    • 35648993031 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2007, 46, 8050.
    • (2007) Chem. Int. Ed , vol.46 , pp. 8050
    • Angew1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.