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Volumn 31, Issue 24, 2012, Pages 8561-8570

Impact of backbone substituents on POCOP-Ni pincer complexes: A structural, spectroscopic, and electrochemical study

Author keywords

[No Author keywords available]

Indexed keywords

DONOR MOIETY; ELECTROCHEMICAL STUDIES; LIGAND FIELD; MULTINUCLEAR NMR; OXIDATION POTENTIALS; PINCER COMPLEXES; PINCER-TYPE LIGAND; RED SHIFT; ROOM TEMPERATURE; SINGLE CRYSTAL X-RAY DIFFRACTION; STRUCTURAL DATA; UV-VIS SPECTRA; UV-VIS SPECTROSCOPY; VOLTAMMETRY MEASUREMENTS;

EID: 84871596517     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om3009475     Document Type: Article
Times cited : (62)

References (70)
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    • In the case of low-yielding reactions, NMR spectra of the final reaction mixtures did not show any unreacted ligands. We have no definitive explanation at this point for the observed low yields other than the possibility that the chelated intermediates formed in these cases decompose into intractable dimeric or polymeric species instead of proceeding to nickellation. For a discussion of related reactions leading to non-metallated species see
    • In the case of low-yielding reactions, NMR spectra of the final reaction mixtures did not show any unreacted ligands. We have no definitive explanation at this point for the observed low yields other than the possibility that the chelated intermediates formed in these cases decompose into intractable dimeric or polymeric species instead of proceeding to nickellation. For a discussion of related reactions leading to non-metallated species see: Pandarus, V.; Castonguay, A.; Zargarian, D. J. Chem. Soc., Dalton Trans. 2008, 4756-4761
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.