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Volumn 23, Issue 8, 2004, Pages 1652-1655

CO Insertion Reactions into the M-OH Bonds of Monomeric Nickel and Palladium Hydroxides. Reversible Decarbonylation of a Hydroxycarbonyl Palladium Complex

Author keywords

[No Author keywords available]

Indexed keywords

CARBON MONOXIDE; CATALYSTS; CHEMICAL BONDS; COMPLEXATION; CRYSTAL STRUCTURE; MONOMERS; NICKEL; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PALLADIUM; RESONANCE; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

EID: 2342430013     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om040002i     Document Type: Article
Times cited : (140)

References (41)
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    • 0000122198 scopus 로고    scopus 로고
    • special issue on bioinorganic enzymology
    • Chem. Rev. 1996, 96, 2237 (special issue on bioinorganic enzymology, edited by R. H. Holm and E. I. Solomon).
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    • Holm, R.H.1    Solomon, E.I.2
  • 2
    • 0003616618 scopus 로고    scopus 로고
    • Cornils, B., Herrmann, W. A., Eds.; VCH: Weinheim, Germany
    • See for example: (a) Jira, R. In Applied Homogeneous Catalysis with Organometallic Compounds, 2nd ed.; Cornils, B., Herrmann, W. A., Eds.; VCH: Weinheim, Germany, 2002. (b) Breno, K. L.; Pluth, M. D.; Tyler, D. R. Organometallics 2003, 22, 1203.
    • (2002) Applied Homogeneous Catalysis with Organometallic Compounds, 2nd Ed.
    • Jira, R.1
  • 3
    • 0037451074 scopus 로고    scopus 로고
    • See for example: (a) Jira, R. In Applied Homogeneous Catalysis with Organometallic Compounds, 2nd ed.; Cornils, B., Herrmann, W. A., Eds.; VCH: Weinheim, Germany, 2002. (b) Breno, K. L.; Pluth, M. D.; Tyler, D. R. Organometallics 2003, 22, 1203.
    • (2003) Organometallics , vol.22 , pp. 1203
    • Breno, K.L.1    Pluth, M.D.2    Tyler, D.R.3
  • 12
    • 2342435570 scopus 로고    scopus 로고
    • note
    • A search in the CCDC database (version 5.24, July 2003) afforded 54 structures of discrete Ni and Pd complexes containing μ-OH ligands.
  • 18
    • 2342432821 scopus 로고    scopus 로고
    • note
    • 2) as starting material.
  • 19
    • 2342430334 scopus 로고    scopus 로고
    • note
    • 1/c, α = 8.9176(10) Å, b = 25.106(3) Å, c = 10.5817(12) Å, α = 90°, β= 111.011(2)°, γ = 90°, V = 2211.6(4) Å, Z = 4. The final R factor was 0.0372 for 5107 independent reflections with I > 2σ(I) (wR2 = 0.0752). GOF = 0.950.
  • 25
    • 2342423694 scopus 로고    scopus 로고
    • note
    • 1/n, α = 16.706(6) Å, b = 13.192(5) Å, c = 20.320(8) Å, α = 90°, β= 98.004(7)°, γ = 90°, V = 4435(3) Å, Z = 4. The final R factor was 0.0648 for 5802 independent reflections with I > 2σ(I) (wR2 = 0.1320). GOF = 0.946.
  • 28
    • 2342421282 scopus 로고    scopus 로고
    • note
    • 2-C,O) (2a), was washed with cooled hexane (2 × 1 mL) and dried under vacuum. Yield: 60%.
  • 29
    • 2342429429 scopus 로고    scopus 로고
    • note
    • 2C,O) (2b) was obtained, after addition of some hexane and cooling to -30°C, as a white microcrystalline solid. Yield: 50%.
  • 31
    • 2342432505 scopus 로고    scopus 로고
    • note
    • 2, fw 931.65, monodinic, space group C2/c, α = 21.6438(3) Å, b = 10.85640(10) Å, c = 20.8083(2) Å, α = 90°, β= 111.3890(10)°, γ = 90°, V = 4552.65(7) Å, Z = 4. The final R factor was 0.0277 for 4093 independent reflections with I > 2σ(I) (wR2 = 0.0743). GOF = 1.032.
  • 32
    • 0000656657 scopus 로고    scopus 로고
    • See for instance: (a) Szalda, D. J.; Chou, M. H.; Fujita, E.; Creutz, C. Inorg. Chem. 1992, 31, 4712. (b) Gibson, D. H.; Sleadd, B. A.; Mashuta, M. S.; Richardson, J. F. Organometallics 1997, 16, 4421. (c) Gibson, D. H.; Ding, Y.; Andino, J. G.; Mashuta, M. S.; Richardson, J. F. Organometallics 1998, 17, 1998.
    • (1992) Inorg. Chem. , vol.31 , pp. 4712
    • Szalda, D.J.1    Chou, M.H.2    Fujita, E.3    Creutz, C.4
  • 33
    • 0000702957 scopus 로고    scopus 로고
    • See for instance: (a) Szalda, D. J.; Chou, M. H.; Fujita, E.; Creutz, C. Inorg. Chem. 1992, 31, 4712. (b) Gibson, D. H.; Sleadd, B. A.; Mashuta, M. S.; Richardson, J. F. Organometallics 1997, 16, 4421. (c) Gibson, D. H.; Ding, Y.; Andino, J. G.; Mashuta, M. S.; Richardson, J. F. Organometallics 1998, 17, 1998.
    • (1997) Organometallics , vol.16 , pp. 4421
    • Gibson, D.H.1    Sleadd, B.A.2    Mashuta, M.S.3    Richardson, J.F.4
  • 34
    • 0000656657 scopus 로고    scopus 로고
    • See for instance: (a) Szalda, D. J.; Chou, M. H.; Fujita, E.; Creutz, C. Inorg. Chem. 1992, 31, 4712. (b) Gibson, D. H.; Sleadd, B. A.; Mashuta, M. S.; Richardson, J. F. Organometallics 1997, 16, 4421. (c) Gibson, D. H.; Ding, Y.; Andino, J. G.; Mashuta, M. S.; Richardson, J. F. Organometallics 1998, 17, 1998.
    • (1998) Organometallics , vol.17 , pp. 1998
    • Gibson, D.H.1    Ding, Y.2    Andino, J.G.3    Mashuta, M.S.4    Richardson, J.F.5
  • 35
    • 2342418904 scopus 로고    scopus 로고
    • note
    • 2}(COOH) (3b; 90% yield).


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