Cu-Catalyzed silylation of alkynes: A traceless 2-pyridylsulfonyl controller allows access to either regioisomer on demand

Journal of the American Chemical Society

Volumn 137, Issue 21, 2015, Pages 6857-6865

  García Rubia, Alfonso ^a   Romero Revilla, Jose A ^a   Mauleón, Pablo ^a   Gómez Arrayás, Ramón ^a   Carretero, Juan C ^a  

^a UNIVERSIDAD AUTÓNOMA DE MADRID   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; HYDROSILYLATION; SILANES;

CHEMO-SELECTIVITY; INTERNAL ALKYNES; NEW APPROACHES; REACTION EFFICIENCY; REGIOCHEMICAL; SILYLCUPRATION; STEREOCONTROL; SULFONYL GROUPS;

HYDROCARBONS;

ALKYNE DERIVATIVE; ALLENE DERIVATIVE; COPPER; COPPER COMPLEX; PYRIDINE DERIVATIVE; SULFONE DERIVATIVE;

ARTICLE; CATALYSIS; DECOMPOSITION; DIASTEREOISOMER; HYDROBORATION; HYDROSILYLATION; ISOMER; NUCLEAR OVERHAUSER EFFECT; PROTON NUCLEAR MAGNETIC RESONANCE; RATE CONSTANT; SILYLATION; STEREOCHEMISTRY; STEREOSPECIFICITY; SUBSTITUTION REACTION; TEMPERATURE;

EID: 84930624315     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b02667     Document Type: Article

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