Enantioselective ruthenium-catalyzed carbonyl allylation via alkyne-alcohol C-C bond-forming transfer hydrogenation: Allene hydrometalation vs oxidative coupling

Journal of the American Chemical Society

Volumn 137, Issue 9, 2015, Pages 3161-3164

  Liang, Tao ^a   Nguyen, Khoa D ^a   Zhang, Wandi ^a   Krische, Michael J ^a  

^a University of Texas at Austin   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYLATION; HYDROCARBONS; RUTHENIUM; RUTHENIUM COMPOUNDS;

C-C BOND FORMING; CARBONYL ALLYLATION; ENANTIOSELECTIVE; HOMOALLYLIC ALCOHOL; OXIDATIVE COUPLINGS; PRIMARY ALCOHOLS; RUTHENIUM COMPLEXES; TRANSFER HYDROGENATIONS;

ENANTIOSELECTIVITY;

ALCOHOL; ALKYNE; ALLENE DERIVATIVE; CARBON; CARBONYL DERIVATIVE; RUTHENIUM; ALCOHOL DERIVATIVE; ALKADIENE; ALLYL COMPOUND; PROPADIENE;

ALLYLATION; ARTICLE; CATALYSIS; CHEMICAL BOND; DIASTEREOISOMER; ENANTIOSELECTIVITY; HYDROGENATION; ISOMERIZATION; OXIDATION; OXIDATIVE COUPLING; STEREOCHEMISTRY; X RAY DIFFRACTION; CHEMISTRY; OXIDATION REDUCTION REACTION; STEREOISOMERISM;

ALCOHOLS; ALKADIENES; ALKYNES; ALLYL COMPOUNDS; CATALYSIS; HYDROGENATION; OXIDATION-REDUCTION; RUTHENIUM; STEREOISOMERISM;

EID: 84924664057     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b00747     Document Type: Article

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