(E)- and (Z)-β-borylallylsilanes by alkyne silaboration followed by regio- and stereoselective double-bond migration

Angewandte Chemie - International Edition

Volumn 50, Issue 52, 2011, Pages 12501-12504

  Ohmura, Toshimichi ^a   Oshima, Kazuyuki ^a   Suginome, Michinori ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

boron; homogeneous catalysis; isomerization; palladium; silicon

Indexed keywords

HOMOGENEOUS CATALYSIS; REGIO-SELECTIVE; SILABORATION; STEREO-SELECTIVE; TERMINAL ALKYNE;

BORON; BORON COMPOUNDS; CATALYSIS; ISOMERIZATION; PALLADIUM; REACTION KINETICS; SILICON; STEREOSELECTIVITY;

ACETYLENE;

ALKYNE; BORON DERIVATIVE; SILANE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

ALKYNES; BORON COMPOUNDS; MOLECULAR STRUCTURE; SILANES; STEREOISOMERISM;

EID: 84255198634     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201106077     Document Type: Article

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