Ligand-controlled remarkable regio- and stereodivergence in intermolecular hydrosilylation of internal alkynes: Experimental and theoretical studies

Journal of the American Chemical Society

Volumn 135, Issue 37, 2013, Pages 13835-13842

  Ding, Shengtao ^a   Song, Li Juan ^b   Chung, Lung Wa ^a   Zhang, Xinhao ^b   Sun, Jianwei ^a   Wu, Yun Dong ^b,c  

^a HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Hong Kong)

^b PEKING UNIVERSITY   (China)

^c PEKING UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

EXPERIMENTAL EVIDENCE; HIGH SELECTIVITY; HYDROSILYLATIONS; INTERNAL ALKYNES; RUTHENIUM COMPLEXES; THEORETICAL STUDY; TRANSITION STATE; VERSATILE PRODUCTS;

HYDROCARBONS; HYDROSILYLATION; LIGANDS; RUTHENIUM COMPOUNDS; STEREOSELECTIVITY;

CHELATION;

ALKYNE DERIVATIVE; LIGAND; RUTHENIUM COMPLEX; VINYL DERIVATIVE;

ARTICLE; BUILDING; CALCULATION; CATALYST; DENSITY FUNCTIONAL THEORY; DERIVATIZATION; ENERGY TRANSFER; HYDROSILYLATION; ISOMERIZATION; STEREOCHEMISTRY; THEORETICAL STUDY;

ALKYNES; CATALYSIS; COORDINATION COMPLEXES; LIGANDS; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR STRUCTURE; RUTHENIUM; SILANES; STEREOISOMERISM;

EID: 84884467609     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja405752w     Document Type: Article

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