Hydrosilylation of ketones, imines and nitriles catalysed by electrophilic phosphonium cations: Functional group selectivity and mechanistic considerations

Chemistry - A European Journal

Volumn 21, Issue 17, 2015, Pages 6491-6500

  Pérez, Manuel ^a   Qu, Zheng Wang ^b   Caputo, Christopher B ^a   Podgorny, Vitali ^a   Hounjet, Lindsay J ^a   Hansen, Andreas ^b   Dobrovetsky, Roman ^a   Grimme, Stefan ^b   Stephan, Douglas W ^a,c  

^a UNIVERSITY OF TORONTO   (Canada)

^b UNIVERSITY OF BONN   (Germany)

^c KING ABDULAZIZ UNIVERSITY   (Saudi Arabia)

Author keywords

homogeneous catalysis; hydrosilylation; phosphonium; reaction mechanisms; selectivity

Indexed keywords

CATALYSIS; CATALYST SELECTIVITY; CATALYSTS; FUNCTIONAL GROUPS; HYDROSILYLATION; KETONES; NITROGEN COMPOUNDS; POSITIVE IONS; REACTION KINETICS;

ACTIVATED COMPLEX; COMPUTATIONAL STUDIES; HOMOGENEOUS CATALYSIS; PHOSPHONIUM; PHOSPHONIUM CATIONS; PHOSPHONIUM SALTS; REACTION MECHANISM; ROOM TEMPERATURE;

CYANIDES;

EID: 84926668160     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201406356     Document Type: Article

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