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Volumn 126, Issue 42, 2004, Pages 13794-13807

Preparation and molecular and electronic structures of iron(0) dinitrogen and silane complexes and their application to catalytic hydrogenation and hydrosilation

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; COMPOSITION; ELECTRONIC STRUCTURE; HYDROGENATION; MOLECULAR STRUCTURE; OLEFINS; SILANES; SODIUM COMPOUNDS;

EID: 6444222176     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja046753t     Document Type: Article
Times cited : (731)

References (114)
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    • Early-transition-metal and lanthanide catalysts are also effective for hydrogenation and hydrosilation. For representative examples see: (a) Troutman, M. V.; Apella, D. H.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 4916. (b) Conticello, V. P.; Brard, L.; Giardello, M. A.; Tsuji, Y.; Sabat, M.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1992, 114, 2761. (c) Jeske, G.; Lauke, H.; Mauermann, H.; Schumann, H.; Marks, T. J. J. Am. Chem. Soc. 1985, 107, 8111.
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    • Early-transition-metal and lanthanide catalysts are also effective for hydrogenation and hydrosilation. For representative examples see: (a) Troutman, M. V.; Apella, D. H.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 4916. (b) Conticello, V. P.; Brard, L.; Giardello, M. A.; Tsuji, Y.; Sabat, M.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1992, 114, 2761. (c) Jeske, G.; Lauke, H.; Mauermann, H.; Schumann, H.; Marks, T. J. J. Am. Chem. Soc. 1985, 107, 8111.
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    • note
    • Although !-(NI)I loses 1 equiv of dinitrogen in solution, we will refer to the precatalyst as 1-(N2)I throughout the paper as this is the compound that is isolated and charged into the catalytic reactions.
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