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Volumn 53, Issue 5, 1997, Pages 1627-1634

Reduction of carbonyl compounds by using polymethylhydrosiloxane: Reactivity and selectivity

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE; CARBONYL DERIVATIVE; FUNCTIONAL GROUP; KETONE; SILOXANE; TETRAHYDROFURAN;

EID: 0031550590     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(96)01092-7     Document Type: Article
Times cited : (70)

References (49)
  • 6
    • 0000533235 scopus 로고
    • (e) Fujita, M.; Hiyama, T. J. Am. Chem. Soc. 1984, 106, 4629-4630 and J. Org. Chem. 1988, 53, 5405-5415.
    • (1988) J. Org. Chem. , vol.53 , pp. 5405-5415
  • 8
    • 0009142699 scopus 로고
    • (f) Idem, J. Am. Chem. Soc. 1985, 107, 8294-8296 and J. Org. Chem. 1988, 53, 5415-5421.
    • (1988) J. Org. Chem. , vol.53 , pp. 5415-5421
  • 15
    • 0010158798 scopus 로고    scopus 로고
    • and references cited in these publications
    • (m) Kobayashi, S.; Yasuda, M.; Hachiya, I. Chem. Lett. 1996, 407-408, and references cited in these publications.
    • (1996) Chem. Lett. , pp. 407-408
    • Kobayashi, S.1    Yasuda, M.2    Hachiya, I.3
  • 17
    • 0002945089 scopus 로고
    • 3. For the reduction of carbonyl compounds: see references 4-7. Other reports using PMHS as the reducing reagent: (a) Nitzsche, S.; Wick, M. Angew. Chem. 1957, 69, 96.
    • (1957) Angew. Chem. , vol.69 , pp. 96
    • Nitzsche, S.1    Wick, M.2
  • 30
    • 0011292533 scopus 로고    scopus 로고
    • note
    • 2 were not efficient.
  • 32
    • 0011292707 scopus 로고    scopus 로고
    • note
    • 10. According to the referee a reduction of the ketone 1 by using 1,1,3,3-tetramethyldisiloxane was examined under the identical conditions to give similar results (89% yield, trans : cis = 97 : 3). However, the reagent is 6 fold more expensive than PMHS based on the hydride involved.
  • 33
    • 0011325803 scopus 로고    scopus 로고
    • note
    • 4 was carried out under otherwise identical conditions. The published ratios are ca 90 : 10, see ref 12.
  • 45
    • 0003601534 scopus 로고    scopus 로고
    • Merck: New Jersey
    • 20. Data from The MERCK INDEX, 12th Ed.; Merck: New Jersey, 1996.
    • (1996) The MERCK INDEX, 12th Ed.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.