Mechanistic studies on the metal-free activation of dihydrogen by antiaromatic pentarylboroles

Journal of the American Chemical Society

Volumn 135, Issue 2, 2013, Pages 941-947

  Houghton, Adrian Y ^a   Karttunen, Virve A ^b   Fan, Cheng ^a   Piers, Warren E ^a   Tuononen, Heikki M ^b  

^a UNIVERSITY OF CALGARY   (Canada)

^b UNIVERSITY OF JYVÄSKYLÄ   (Finland)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION PARAMETER; ANTIAROMATICITY; BOND CLEAVAGES; DIHYDROGEN; FIRST-ORDER; KINETIC ISOTOPE EFFECTS; KINETIC PROPERTIES; LEWIS ACID; MAIN GROUP; MECHANISTIC STUDIES; NEW MECHANISMS; PROCESS-DRIVEN; RATE LIMITING; REACTION MECHANISM; RING OPENING; TO EFFECT; TRANSITION STATE;

ISOTOPES;

STEREOCHEMISTRY;

BORON DERIVATIVE; HYDROGEN; LEWIS ACID; PENTAARYLBOROLE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; DENSITY FUNCTIONAL THEORY; ELECTRON; GEOMETRY; HYDROGEN BOND; PROTON NUCLEAR MAGNETIC RESONANCE; RING CLOSING METATHESIS; RING OPENING; STEREOCHEMISTRY; SYNTHESIS;

EID: 84872581199     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja311842r     Document Type: Article

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