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Volumn 34, Issue 5, 2015, Pages 953-966

Palladium-catalyzed direct ortho aroylation of 2-phenoxypyridines with aldehydes and catalytic mechanism investigation

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDES; ISOTOPES; KETONES; ORGANOMETALLICS; PALLADIUM COMPOUNDS;

EID: 84924386262     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om501330h     Document Type: Article
Times cited : (46)

References (71)
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    • 84863446276 scopus 로고    scopus 로고
    • Regarding the formation of diaroylated products such as 4a, b, p and even 4u (see Table 2) and 7b, f, g, j (see Table 3) in the reaction, we suspect that the "weak interaction" in the second direct aroylation process might play as an important factor. Please see the presentation below and refer to the review paper on the discussion of "weak coordination in the direct C-H functionalization"
    • Regarding the formation of diaroylated products such as 4a, b, p and even 4u (see Table 2) and 7b, f, g, j (see Table 3) in the reaction, we suspect that the "weak interaction" in the second direct aroylation process might play as an important factor. Please see the presentation below and refer to the review paper on the discussion of "weak coordination in the direct C-H functionalization": Engle, K. M.; Mei, T.-S.; Wasa, M.; Yu, J.-Q. Acc. Chem. Res. 2012, 45, 788-802
    • (2012) Acc. Chem. Res. , vol.45 , pp. 788-802
    • Engle, K.M.1    Mei, T.-S.2    Wasa, M.3    Yu, J.-Q.4
  • 64
    • 84924377990 scopus 로고    scopus 로고
    • Copies of the deposited crystallographic data (CCDC-1041437 (3d), CCDC-1041438 (4a), and CCDC-1041439 (11c)) can be obtained free of charge from The Cambridge Crystallographic Data Centre via.
    • Copies of the deposited crystallographic data (CCDC-1041437 (3d), CCDC-1041438 (4a), and CCDC-1041439 (11c)) can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
  • 68
    • 84858776560 scopus 로고    scopus 로고
    • For an interpretation of kinetic isotope effects on the transition-metal-catalyzed direct C-H functionalization, see: Simmons, E. M.; Hartwig, J. F. Angew. Chem., Int. Ed. 2012, 51, 3066-3072
    • (2012) Angew. Chem., Int. Ed. , vol.51 , pp. 3066-3072
    • Simmons, E.M.1    Hartwig, J.F.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.