Regioselective oxidative trifluoromethylation of imidazoheterocycles via C(sp2)-H bond functionalization

Journal of Organic Chemistry

Volumn 80, Issue 3, 2015, Pages 1332-1337

  Monir, Kamarul ^a   Bagdi, Avik Kumar ^a   Ghosh, Monoranjan ^a   Hajra, Alakananda ^a  

^a VISVA BHARATI UNIVERSITY   (India)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMISTRY; ORGANIC COMPOUNDS;

AMBIENT AIR; C-H BOND; FUNCTIONALIZATIONS; IMIDAZOPYRIDINES; IMIDAZO[2 ,1-B]THIAZOLE; REGIO-SELECTIVE; TRIFLUOROMETHYL; TRIFLUOROMETHYLATION;

PYRIDINE;

1 [4 [7 METHYL 3 (TRIFLUOROMETHYL)IMIDAZO[1,2 A]PYRIDIN 2 YL]PHENYL]ETHANONE; 2 (3 BROMOPHENYL) 3 (TRIFLUOROMETHYL)IMIDAZO[1,2 A]PYRIDINE; 2 (4 CHLOROPHENYL) 8 (TRIFLUOROMETHYL)IMIDAZO[1,2 A]PYRIDINE; 2 (4 CHLOROPHENYL) 8 METHYL 3 (TRIFLUOROMETHYL)IMIDAZO[1,2 A]PYRIDINE; 2 (4 METHOXYPHENYL) 3 (TRIFLUOROMETHYL)IMIDAZO[1,2 A]PYRIDINE; 2 (PYRIDIN 2 YL) 3 (TRIFLUOROMETHYL)IMIDAZO[1,2 A]PYRIDINE; 2 P TOLYL 3 (TRIFLUOROMETHYL)IMIDAZO[1,2 A]PYRIDINE; 2 PHENYL 3 (TRIFLUOROMETHYL)BENZO[D]IMIDAZO[2,1 B]THIAZOLE; 2 PHENYL 3 (TRIFLUOROMETHYL)IMIDAZO[1,2 A]PYRIDINE; 2 [4 (ALLYLOXY)PHENYL] 3 (TRIFLUOROMETHYL)BENZO[D]IMIDAZO[2,1 B]THIAZOLE; 2 [4 (METHYLSULFONYL)PHENYL] 3 (TRILFUOROMETHYL)IMIDAZO[1,2 A]PYRIDINE; 4 [3 (TRILFUOROMETHYL)IMIDAZO[1,2 A]PYRIDINE 2 YL]BENZONITRILE; 6 BROMO 2 PHENYL 3 (TRIFLUOROMETHYL)IMIDAZO[1,2 A]PYRIDINE; 6 CHLORO 2 PHENYL 3 (TRIFLUOROMETHYL)IMIDAZO[1,2 A]PYRIDINE; 6 PHENYL 5 (TRIFLUOROMETHYL)IMIDAZO[2,1 B]THIAZOLE; 7 METHYL 2 (3 NITROPHENYL) 3 (TRIFLUOROMETHYL)IMIDAZO[1,2 A]PYRIDINE; 7 METHYL 2 (THIOPHENE 2 YL) 3 (TRIFLUOROMETHYL)IMIDAZO[1,2 A ]PYRIDINE; 7 METHYL 2 P TOLYL 3 (TRIFLUOROMETHYL)IMIDAZO[1,2 A]PYRIDINE; 7 METHYL 2 PHENYL 3 (TRIFLUOROMETHYL)IMIDAZO[1,2 A]PYRIDINE; 7 METHYL 3 (TRIFLUOROMETHYL) 2 [4 (TRIFLUOROMETHYL)PHENYL]IMIDAZO[1,2 A]PYRIDINE; 8 METHYL 2 PHENYL 3 (TRIFLUOROMETHYL)IMIDAZO[1,2 A]PYRIDINE; IMIDAZOPYRIDINE DERIVATIVE; LANGLOIS REAGENT; METHYL GROUP; ORGANOFLUORINE DERIVATIVE; PHENYL GROUP; REAGENT; SILVER NITRATE; THIAZOLE DERIVATIVE; UNCLASSIFIED DRUG; BENZO(D)IMIDAZO(2,1-B)THIAZOLE; IMIDAZO(2,1-B)THIAZOLE; IMIDAZOLE DERIVATIVE; PYRIDINE DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; COVALENT BOND; DRUG SYNTHESIS; METHODOLOGY; METHYLATION; OXIDATION; REGIOSELECTIVITY; TRIFLUOROMETHYLATION; CHEMICAL STRUCTURE; CHEMISTRY; HYDROGEN BOND; OXIDATION REDUCTION REACTION; STEREOISOMERISM; SYNTHESIS;

CATALYSIS; HYDROGEN BONDING; IMIDAZOLES; METHYLATION; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; PYRIDINES; STEREOISOMERISM; THIAZOLES;

EID: 84922750051     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo502928e     Document Type: Article

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