How does tunneling contribute to counterintuitive H-abstraction reactivity of nonheme Fe(IV)O oxidants with alkanes?

Journal of the American Chemical Society

Volumn 137, Issue 2, 2015, Pages 722-733

  Mandal, Debasish ^a   Ramanan, Rajeev ^a   Usharani, Dandamudi ^a,b   Janardanan, Deepa ^a,c   Wang, Binju ^a   Shaik, Sason ^a  

^a HEBREW UNIVERSITY OF JERUSALEM   (Israel)

^b CENTRAL FOOD TECHNOLOGICAL RESEARCH INSTITUTE   (India)

^c CENTRAL UNIVERSITY OF KERALA   (India)

Author keywords

[No Author keywords available]

Indexed keywords

ABSTRACTING; BIOCHEMISTRY; CHEMICAL BONDS; LIGANDS; PHOSPHORUS COMPOUNDS;

1 ,4-CYCLOHEXADIENES; BIOINORGANIC CHEMISTRY; CH-BOND ACTIVATION; HYDROGEN ABSTRACTION; KINETIC ISOTOPE EFFECTS; REACTIVITY PATTERN; TRIPHENYL PHOSPHINES; TWO-STATE REACTIVITY;

IRON COMPOUNDS;

1,4 CYCLOHEXADIENE; 9,10 DIHYDROANTHRACENE; ALKANE DERIVATIVE; ANTHRACENE DERIVATIVE; CARBON; FERRIC OXIDE; HYDROGEN; ISOTOPE; LIGAND; OXIDIZING AGENT; UNCLASSIFIED DRUG; ALKANE; IRON; OXYGEN;

ARTICLE; CALCULATION; CHEMICAL REACTION; COMPLEX FORMATION; CONTROLLED STUDY; ELECTRON; ELECTROPHILICITY; GEOMETRY; HYDROGEN ABSTRACTION; HYDROGEN BOND; KINETIC ISOTOPE EFFECT; KINETICS; OXIDATION; OXYGEN TRANSPORT; ROOM TEMPERATURE; SOLVATION; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; QUANTUM THEORY;

ALKANES; HYDROGEN; IRON; KINETICS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; OXIDANTS; OXYGEN; QUANTUM THEORY;

EID: 84921506796     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja509465w     Document Type: Article

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