Tunneling in C-H oxidation reactions by an oxoiron(IV) porphyrin radical cation: Direct measurements of very large H/D kinetic isotope effects

Journal of the American Chemical Society

Volumn 130, Issue 25, 2008, Pages 7776-7777

  Pan, Zhengzheng ^a   Horner, John H ^a   Newcomb, Martin ^a  

^a UNIVERSITY OF ILLINOIS AT CHICAGO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; CATION; HYDROGEN; IRON DERIVATIVE; ISOTOPE; PORPHYRIN; RADICAL;

ARTICLE; HYDROXYLATION; KINETICS; OXIDATION; REACTION ANALYSIS; TEMPERATURE DEPENDENCE; ULTRAVIOLET SPECTROSCOPY;

BENZYL ALCOHOL; CARBON; DEUTERIUM; HYDROGEN; IRON; ISOTOPES; KINETICS; OXIDATION-REDUCTION; PORPHYRINS;

EID: 45749107161     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja802484n     Document Type: Article

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