Kinetic solvent effects on the reactions of the cumyloxyl radical with tertiary amides. control over the hydrogen atom transfer reactivity and selectivity through solvent polarity and hydrogen bonding

Journal of Organic Chemistry

Volumn 80, Issue 2, 2015, Pages 1149-1154

  Salamone, Michela ^a   Mangiacapra, Livia ^a   Bietti, Massimo ^a  

^a UNIVERSITY OF ROME TOR VERGATA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

AMIDES; ATOM LASERS; ATOMS; FREE RADICAL REACTIONS; HYDROGEN; ORGANIC SOLVENTS; PARAFFINS; PHOTOLYSIS; POLYOLS; RATE CONSTANTS; SOLVENTS;

DIPOLE DIPOLE INTERACTIONS; ELECTRON DEFICIENCY; HYDROGEN ATOM TRANSFERS (HAT); HYDROGEN-ATOM TRANSFER; LASER FLASH PHOTOLYSIS; N ,N-DIMETHYLACETAMIDE; N ,N-DIMETHYLFORMAMIDE; REACTION SELECTIVITY;

HYDROGEN BONDS;

AMIDE; CARBON; HYDROGEN; N FORMYLPYRROLIDINE; N,N DIMETHYLACETAMIDE; N,N DIMETHYLFORMAMIDE; PYRROLIDINE DERIVATIVE; RADICAL; SOLVENT; UNCLASSIFIED DRUG; ACETAMIDE DERIVATIVE;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL INTERACTION; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; DIPOLE; ELECTRON; ELECTROPHILICITY; HYDROGEN BOND; KINETICS; PHOTOLYSIS; POLARIZATION; PROTON TRANSPORT; SOLVENT EFFECT; CHEMICAL STRUCTURE; CHEMISTRY;

ACETAMIDES; AMIDES; DIMETHYLFORMAMIDE; HYDROGEN BONDING; KINETICS; MOLECULAR STRUCTURE; PYRROLIDINES; SOLVENTS;

EID: 84921326735     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo5026767     Document Type: Article

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