Iron(IV)hydroxide pKa and the role of thiolate ligation in C-H bond activation by cytochrome P450

Science

Volumn 342, Issue 6160, 2013, Pages 825-829

  Yosca, Timothy H ^a   Rittle, Jonathan ^a   Krest, Courtney M ^a   Onderko, Elizabeth L ^a   Silakov, Alexey ^a   Calixto, Julio C ^a   Behan, Rachel K ^a   Green, Michael T ^a  

^a PENNSYLVANIA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CYTOCHROME P450; FERRIC HYDROXIDE; HISTIDINE; HYDROCARBON; PHENYLALANINE; THIOL DERIVATIVE; TRYPTOPHAN; TYROSINE;

CATALYST; CHEMICAL BONDING; CYTOCHROME; ENZYME ACTIVITY; IRON HYDROXIDE; ORGANIC SULFUR COMPOUND; OXIDATION; PROTEIN;

ARTICLE; AUTOOXIDATION; CHEMICAL BOND; CONFORMATIONAL TRANSITION; DIELECTRIC CONSTANT; DISSOCIATION; ELECTRON; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; ELECTROPHILICITY; HYDROGEN BOND; OXIDATION REDUCTION POTENTIAL; PKA; PRIORITY JOURNAL; SITE DIRECTED MUTAGENESIS; ULTRAVIOLET IRRADIATION; X RAY ABSORPTION SPECTROSCOPY;

EID: 84887761225     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1244373     Document Type: Article

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