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Volumn 33, Issue 21, 2014, Pages 6113-6121

Activation of dihydrogen and silanes by cationic iron bis(phosphinite) pincer complexes

Author keywords

[No Author keywords available]

Indexed keywords

ALKALINITY; CARBON DIOXIDE; CATALYST ACTIVITY; HYDRIDES; HYDROSILYLATION; KETONES; PROTONATION; SILANES;

EID: 84910008007     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om500758j     Document Type: Article
Times cited : (37)

References (82)
  • 3
    • 35848964033 scopus 로고    scopus 로고
    • Kubas, G. J. Chem. Rev. 2007, 107, 4152-4205
    • (2007) Chem. Rev. , vol.107 , pp. 4152-4205
    • Kubas, G.J.1
  • 12
  • 47
    • 84891017826 scopus 로고    scopus 로고
    • Ionic Hydrogenations
    • de Vries, J. G. Elsevier, C. J. Wiley-VCH: Weinheim, Germany
    • Bullock, R. M. Ionic Hydrogenations. In The Handbook of Homogeneous Hydrogenation; de Vries, J. G.; Elsevier, C. J., Eds.; Wiley-VCH: Weinheim, Germany, 2007; pp 153-197.
    • (2007) The Handbook of Homogeneous Hydrogenation , pp. 153-197
    • Bullock, R.M.1
  • 49
    • 84900811961 scopus 로고    scopus 로고
    • A very recent mechanistic study has shown that the most active hydride intermediate is not the hydride species produced after silylium transfer, but a silane-bound iridium hydride. For details, see: Metsanen, T. T.; Hrobárik, P.; Klare, H. F. T.; Kaupp, M.; Oestreich, M. J. Am. Chem. Soc. 2014, 136, 6912-6915
    • (2014) J. Am. Chem. Soc. , vol.136 , pp. 6912-6915
    • Metsanen, T.T.1    Hrobárik, P.2    Klare, H.F.T.3    Kaupp, M.4    Oestreich, M.5
  • 63
    • 23044443893 scopus 로고    scopus 로고
    • 2H in water are 3.75 and 0.52, respectively. These numbers were obtained from the following book: Anslyn, E. V.; Dougherty, D. A. Modern Physical Organic Chemistry; University Science Books: Sausalito, CA, 2006; p 279.
    • (2006) Modern Physical Organic Chemistry , pp. 279
    • Anslyn, E.V.1    Dougherty, D.A.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.