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In the MECP both the energy and the geometry of the molecule are the same in the two spin-state surfaces. Once that point (MECP) is reached, following the reaction coordinate, there is a given probability for the system to change spin state and hop from one PES to the other, giving rise to the "spin-forbidden" reaction
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In the MECP both the energy and the geometry of the molecule are the same in the two spin-state surfaces. Once that point (MECP) is reached, following the reaction coordinate, there is a given probability for the system to change spin state and hop from one PES to the other, giving rise to the "spin-forbidden" reaction.
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