메뉴 건너뛰기




Volumn 29, Issue 21, 2010, Pages 4932-4942

Kinetically controlled formation of octahedral trans -dicarbonyl iron(II) PNP pincer complexes: The decisive role of spin-state changes

Author keywords

[No Author keywords available]

Indexed keywords


EID: 78149354088     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om1001638     Document Type: Article
Times cited : (34)

References (54)
  • 1
    • 0000714026 scopus 로고    scopus 로고
    • For a review of open-shell complexes see
    • For a review of open-shell complexes see: Poli, R. Chem. Rev. 1996, 96, 2135
    • (1996) Chem. Rev. , vol.96 , pp. 2135
    • Poli, R.1
  • 8
    • 22544459013 scopus 로고    scopus 로고
    • Spin Crosso v er in Transition Metal Compounds i
    • Gütlich P., Goodwin H.A. Eds.; Springer-Verlag: Berlin
    • Spin Crosso v er in Transition Metal Compounds I; Topics in Current Chemistry 235; Gütlich, P.; Goodwin, H. A., Eds.; Springer-Verlag: Berlin, 2004.
    • (2004) Topics in Current Chemistry 235
  • 25
    • 78149315099 scopus 로고    scopus 로고
    • In the MECP both the energy and the geometry of the molecule are the same in the two spin-state surfaces. Once that point (MECP) is reached, following the reaction coordinate, there is a given probability for the system to change spin state and hop from one PES to the other, giving rise to the "spin-forbidden" reaction
    • In the MECP both the energy and the geometry of the molecule are the same in the two spin-state surfaces. Once that point (MECP) is reached, following the reaction coordinate, there is a given probability for the system to change spin state and hop from one PES to the other, giving rise to the "spin-forbidden" reaction.
  • 26
    • 33845958847 scopus 로고    scopus 로고
    • For more information about MECP and the kinetics of spin-forbidden reactions see, for example
    • For more information about MECP and the kinetics of spin-forbidden reactions see, for example: Harvey, J. N. Phys. Chem. Chem. Phys. 2007, 9, 331
    • (2007) Phys. Chem. Chem. Phys. , vol.9 , pp. 331
    • Harvey, J.N.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.