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Volumn 47, Issue 22, 2008, Pages 4141-4143

Structural and spectroscopic characterization of an unprecedented cationic transition-metal η1-silane complex

Author keywords

complexes; Coordination mode; End on coordination; Iridium; Silane complexes

Indexed keywords

TRANSITION METALS;

EID: 53549098568     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200705359     Document Type: Article
Times cited : (102)

References (41)
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    • isolated cationic silane σ-complexes without X-ray analysis: b) X. Fang, B. L. Scott, K. D. John, G. J. Kubas, Organometallics 2000, 19, 4141-4149.
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    • Calculations have identified complexes with minima showing smaller Si-M interactions: a C. M. Nagaraja, P. Parameswaran, E. D. Jemmis, B. R. Jagirdar, J. Am. Chem. Soc. 2007, 129, 5587-5596;
    • Calculations have identified complexes with minima showing smaller Si-M interactions: a) C. M. Nagaraja, P. Parameswaran, E. D. Jemmis, B. R. Jagirdar, J. Am. Chem. Soc. 2007, 129, 5587-5596;
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    • A neutral Zr dimer with a linear Si-H-Zr interaction has been observed in solid state but does not persist in solution: G. Ciruelo, T. Cuenca, R. Gómez, R. Gomez-Sal, A. Martin, J. Chem. Soc. Dalton Trans. 2001, 1657-1663
    • A neutral Zr dimer with a linear Si-H-Zr interaction has been observed in solid state but does not persist in solution: G. Ciruelo, T. Cuenca, R. Gómez, R. Gomez-Sal, A. Martin, J. Chem. Soc. Dalton Trans. 2001, 1657-1663.
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    • See Supporting Information for experimental details including complete 1H, 31P and 29Si NMR characterization
    • 29Si NMR characterization.
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    • Si-H <20 Hz for classical H-M-Si interactions, see ref
    • 3SiH.
    • 3SiH , vol.3
    • Usually1
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    • 3, Z = 2, R1 = 0.0246 [I > 2σ(I)]. CCDC 676582 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
    • 3, Z = 2, R1 = 0.0246 [I > 2σ(I)]. CCDC 676582 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
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    • Gaussian 03, Revision D.02; B3LYP; LANL2DZ on Ir(+f polarization); 6-311G** on other atoms. For details regarding the DFT study, see Supporting Information.
    • Gaussian 03, Revision D.02; B3LYP; LANL2DZ on Ir(+f polarization); 6-311G** on other atoms. For details regarding the DFT study, see Supporting Information.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.