Unexpected isomerization of a cis- into a trans-Dihydride Complex. A neutral late transition metal complex as a hydride donor

Organometallics

Volumn 16, Issue 17, 1997, Pages 3786-3793

  Rybtchinski, Boris ^a   Ben David, Yehoshoa ^a   Milstein, David ^a  

^a WEIZMANN INSTITUTE OF SCIENCE   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000582518     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970104r     Document Type: Article

References (51)

1. (a) Pearson, R. G. Chem. Rev. 1985, 85, 41.
2. (b) Simões, J. A. M.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629.
3. (c) Angelici, R. J. Acc. Chem. Res. 1995, 28, 51.
4. (d) Wang, D.; Angelici, R. J. J. Am. Chem. Soc. 1996, 118, 935.
5. (a) Fryzuk, M. D.; MacNeil, P. Organometallics 1983, 2, 682.
6. (b) Immirzi, A.; Musco, A.; Carturan, G.; Belluco, U. Inorg. Chim. Acta 1975, 12, L23.
7. (c) Shaw, B. L.; Uttley, M. F. J. Chem. Soc., Chem. Commun. 1974, 918.
8. (d) Yoshida, T.; Otsuka, S. J. Am. Chem. Soc. 1977, 99, 2134.
9. (e) Paonessa, R. S.; Trogler, W. C. J. Am. Chem. Soc. 1982, 104, 1138.
10. For example see: (a) Sweet, J. R.; Graham, W. A. G. Organometallics 1982, 1, 982. (b) Sullivan, P. B.; Meyer, T. J. Organometallics 1986, 5, 1500. (c) Martin, B. D.; Warner, K. E.; Norton, J. R. J. Am. Chem. Soc. 1986, 108, 33.
11. For example see: (a) Sweet, J. R.; Graham, W. A. G. Organometallics 1982, 1, 982. (b) Sullivan, P. B.; Meyer, T. J. Organometallics 1986, 5, 1500. (c) Martin, B. D.; Warner, K. E.; Norton, J. R. J. Am. Chem. Soc. 1986, 108, 33.
12. For example see: (a) Sweet, J. R.; Graham, W. A. G. Organometallics 1982, 1, 982. (b) Sullivan, P. B.; Meyer, T. J. Organometallics 1986, 5, 1500. (c) Martin, B. D.; Warner, K. E.; Norton, J. R. J. Am. Chem. Soc. 1986, 108, 33.
13. For a review see: (a) Darensbourg, M. Y.; Ash, C. E. Adv. Organomet. Chem. 1987, 27, 1. See also: (b) Kinney, R. J.; Jones, W. D.; Bergman, R. G. J. Am. Chem. Soc. 1978, 100, 7902. (c) Linn, D. E., Jr.; Halpern, J. J. Am. Chem. Soc. 1987, 109, 2969.
14. For a review see: (a) Darensbourg, M. Y.; Ash, C. E. Adv. Organomet. Chem. 1987, 27, 1. See also: (b) Kinney, R. J.; Jones, W. D.; Bergman, R. G. J. Am. Chem. Soc. 1978, 100, 7902. (c) Linn, D. E., Jr.; Halpern, J. J. Am. Chem. Soc. 1987, 109, 2969.
15. For a review see: (a) Darensbourg, M. Y.; Ash, C. E. Adv. Organomet. Chem. 1987, 27, 1. See also: (b) Kinney, R. J.; Jones, W. D.; Bergman, R. G. J. Am. Chem. Soc. 1978, 100, 7902. (c) Linn, D. E., Jr.; Halpern, J. J. Am. Chem. Soc. 1987, 109, 2969.
16. 6 reactivity: (a) Mahoney, W. S.; Brestensky, D. M.; Stryker, J. M. J. Am. Chem. Soc. 1988, 110, 291. (b) Mahoney, W. S.; Stryker, J. M. J. Am. Chem. Soc. 1989, 111, 8818.
17. 6 reactivity: (a) Mahoney, W. S.; Brestensky, D. M.; Stryker, J. M. J. Am. Chem. Soc. 1988, 110, 291. (b) Mahoney, W. S.; Stryker, J. M. J. Am. Chem. Soc. 1989, 111, 8818.
18. (a) Gorla, F.; Venanzi, L. M. Organometallics 1994, 13, 43 and references therein,
19. (b) Gorla, F.; Togni, A.; Venanzi, L. M. Organometallics 1994, 13, 1607.
20. (a) Harrod, J. F.; Gilson, D. F. R.; Charles, R. Can. J. Chem. 1969, 47, 2205.
21. (b) Yagupsky, G.; Brown, C. K.; Wilkinson, J. J. Chem. Soc. A 1970, 1392.
22. (c) Harrod, J. F.; Hamer, G.; Yorke, W. J. Am. Chem. Soc. 1979, 101, 3987.
23. (d) Harrod, J. F.; Yorke, W. Inorg. Chem. 1981, 20, 1156.
24. (e) Malatesta, L.; Caglio, G.; Angoleta, M. J. Chem. Soc. 1965, 6974.
25. (f) Chatt, J.; Coffey, R. S.; Shaw, B. L. J. Chem. Soc. 1965, 7391.
26. 3.
27. Geoffroy, G. L.; Lehman, J. R. Adv. Inorg. Chem. Radiochem. 1977, 189.
28. 13C NMR Data for Organometallic Compounds; Academic Press: New York, 1981.
29. For example see: (a) Johnson, C. E.; Eisenberg, R. J. Am. Chem. Soc. 1985,107, 3148. (b) Deutsch, P. P.; Eisenberg, R. Chem. Rev. 1988, 88, 1147. (c) Eisenberg, R.; Cleary, B. P. J. Am. Chem. Soc. 1995, 117, 3510. (d) Fryzuk, M. D.; MacNeil, P.; Rettig, S. J. Organometallics 1986, 5, 2469.
30. For example see: (a) Johnson, C. E.; Eisenberg, R. J. Am. Chem. Soc. 1985,107, 3148. (b) Deutsch, P. P.; Eisenberg, R. Chem. Rev. 1988, 88, 1147. (c) Eisenberg, R.; Cleary, B. P. J. Am. Chem. Soc. 1995, 117, 3510. (d) Fryzuk, M. D.; MacNeil, P.; Rettig, S. J. Organometallics 1986, 5, 2469.
31. For example see: (a) Johnson, C. E.; Eisenberg, R. J. Am. Chem. Soc. 1985,107, 3148. (b) Deutsch, P. P.; Eisenberg, R. Chem. Rev. 1988, 88, 1147. (c) Eisenberg, R.; Cleary, B. P. J. Am. Chem. Soc. 1995, 117, 3510. (d) Fryzuk, M. D.; MacNeil, P.; Rettig, S. J. Organometallics 1986, 5, 2469.
32. For example see: (a) Johnson, C. E.; Eisenberg, R. J. Am. Chem. Soc. 1985,107, 3148. (b) Deutsch, P. P.; Eisenberg, R. Chem. Rev. 1988, 88, 1147. (c) Eisenberg, R.; Cleary, B. P. J. Am. Chem. Soc. 1995, 117, 3510. (d) Fryzuk, M. D.; MacNeil, P.; Rettig, S. J. Organometallics 1986, 5, 2469.
33. For the reviews on carbon disulfide activation see: (a) Butler, I. S.; Fenster, A. E. J. Organomet. Chem. 1974, 66, 161. (b) Yaneff, P. V. Coord. Chem. Rev. 1977, 183. (c) Ibers, J. A. Chem. Soc. Rev. 1982, 57.
34. For the reviews on carbon disulfide activation see: (a) Butler, I. S.; Fenster, A. E. J. Organomet. Chem. 1974, 66, 161. (b) Yaneff, P. V. Coord. Chem. Rev. 1977, 183. (c) Ibers, J. A. Chem. Soc. Rev. 1982, 57.
35. For the reviews on carbon disulfide activation see: (a) Butler, I. S.; Fenster, A. E. J. Organomet. Chem. 1974, 66, 161. (b) Yaneff, P. V. Coord. Chem. Rev. 1977, 183. (c) Ibers, J. A. Chem. Soc. Rev. 1982, 57.
36. 2 activation: (a) Robinson, S. D.; Sahajpal, A. J. Organomet. Chem. 1975, 99, C65. (b) Roper, W. R.; Town, K G. J. Chem. Soc., Chem. Commun. 1977, 781. (c) Collins, T. J.; Roper, W. R. J. Organomet. Chem. 1978, 159, 73. (d) Mishra, A.; Agarwala, U. C. Inorg. Chim. Acta 1988, 145, 191. (e) Klein, D. P.; Kloster, G. M.; Bergman, R. G. J. Am. Chem. Soc. 1990, 112, 2022. (f) Jones, W. D.; Selmeczy, A. D. Organometallics 1992, 11, 889.
37. 2 activation: (a) Robinson, S. D.; Sahajpal, A. J. Organomet. Chem. 1975, 99, C65. (b) Roper, W. R.; Town, K G. J. Chem. Soc., Chem. Commun. 1977, 781. (c) Collins, T. J.; Roper, W. R. J. Organomet. Chem. 1978, 159, 73. (d) Mishra, A.; Agarwala, U. C. Inorg. Chim. Acta 1988, 145, 191. (e) Klein, D. P.; Kloster, G. M.; Bergman, R. G. J. Am. Chem. Soc. 1990, 112, 2022. (f) Jones, W. D.; Selmeczy, A. D. Organometallics 1992, 11, 889.
38. 2 activation: (a) Robinson, S. D.; Sahajpal, A. J. Organomet. Chem. 1975, 99, C65. (b) Roper, W. R.; Town, K G. J. Chem. Soc., Chem. Commun. 1977, 781. (c) Collins, T. J.; Roper, W. R. J. Organomet. Chem. 1978, 159, 73. (d) Mishra, A.; Agarwala, U. C. Inorg. Chim. Acta 1988, 145, 191. (e) Klein, D. P.; Kloster, G. M.; Bergman, R. G. J. Am. Chem. Soc. 1990, 112, 2022. (f) Jones, W. D.; Selmeczy, A. D. Organometallics 1992, 11, 889.
39. 2 activation: (a) Robinson, S. D.; Sahajpal, A. J. Organomet. Chem. 1975, 99, C65. (b) Roper, W. R.; Town, K G. J. Chem. Soc., Chem. Commun. 1977, 781. (c) Collins, T. J.; Roper, W. R. J. Organomet. Chem. 1978, 159, 73. (d) Mishra, A.; Agarwala, U. C. Inorg. Chim. Acta 1988, 145, 191. (e) Klein, D. P.; Kloster, G. M.; Bergman, R. G. J. Am. Chem. Soc. 1990, 112, 2022. (f) Jones, W. D.; Selmeczy, A. D. Organometallics 1992, 11, 889.
40. 2 activation: (a) Robinson, S. D.; Sahajpal, A. J. Organomet. Chem. 1975, 99, C65. (b) Roper, W. R.; Town, K G. J. Chem. Soc., Chem. Commun. 1977, 781. (c) Collins, T. J.; Roper, W. R. J. Organomet. Chem. 1978, 159, 73. (d) Mishra, A.; Agarwala, U. C. Inorg. Chim. Acta 1988, 145, 191. (e) Klein, D. P.; Kloster, G. M.; Bergman, R. G. J. Am. Chem. Soc. 1990, 112, 2022. (f) Jones, W. D.; Selmeczy, A. D. Organometallics 1992, 11, 889.
41. 2 activation: (a) Robinson, S. D.; Sahajpal, A. J. Organomet. Chem. 1975, 99, C65. (b) Roper, W. R.; Town, K G. J. Chem. Soc., Chem. Commun. 1977, 781. (c) Collins, T. J.; Roper, W. R. J. Organomet. Chem. 1978, 159, 73. (d) Mishra, A.; Agarwala, U. C. Inorg. Chim. Acta 1988, 145, 191. (e) Klein, D. P.; Kloster, G. M.; Bergman, R. G. J. Am. Chem. Soc. 1990, 112, 2022. (f) Jones, W. D.; Selmeczy, A. D. Organometallics 1992, 11, 889.
42. Lindner, E.; Fawzi, R.; Mayer, H. A.; Elchele, K.; Hiller, W. Organometallics 1992, 11, 1033.
43. (a) Albinati, A.; Musco, A.; Carturan, G.; Strukul, G. Inorg. Chim. Acta 1976, 78, 219.
44. (b) Immirzi, A.; Musco, A. Inorg. Chim. Acta 1977, 22, L35
45. -1).
46. Beck, W.; Sünkel, K. Chem. Rev. 1988, 88, 1405.
47. Sargent, A. L.; Hall, M. B.; Guest, M. F. J. Am. Chem. Soc. 1992, 114, 517.
48. (a) Dedieu, A.; Strich, A. Inorg. Chem. 1979, 18, 2940.
49. (b) Saillard, J.-Y.; Hoffmann, R. J. Am. Chem. Soc. 1984, 106, 2006.
50. Wilkinson, G. Inorg. Synth. 1972, 13, 126.
51. Liou, S.-Y. Ph.D. Thesis, The Weizmann Institute of Science, Rehovot, Israel 1996.