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Volumn 8, Issue , 2012, Pages 571-599

8.29 Spectroscopic Analysis: Diastereomeric Derivatization for Spectroscopy

Author keywords

Absolute configuration; Chiral derivatizing agent; Diastereomeric ratio; Enantiomeric excess; NMR spectroscopic analysis

Indexed keywords


EID: 84902423316     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1016/B978-0-08-095167-6.00845-4     Document Type: Chapter
Times cited : (10)

References (197)
  • 6
    • 0034632367 scopus 로고    scopus 로고
    • For an alternative appraoch that uses Cortieu's method to determine ee by derivatisation of a chiral analyte with an achiral deuterated derivatising reagent whose spectra is then determined in a chiral liquid crystal NMR solvent, see
    • Challard P., Bertrand M., Canet I., et al. Org. Lett. 2000, 2:2431-2434. For an alternative appraoch that uses Cortieu's method to determine ee by derivatisation of a chiral analyte with an achiral deuterated derivatising reagent whose spectra is then determined in a chiral liquid crystal NMR solvent, see.
    • (2000) Org. Lett. , vol.2 , pp. 2431-2434
    • Challard, P.1    Bertrand, M.2    Canet, I.3
  • 8
  • 12
    • 0942277395 scopus 로고    scopus 로고
    • and references contained therein
    • See: Seco J.M., Quinoa E., Riguera R. Chem. Rev. 2004, 104:17-117. and references contained therein.
    • (2004) Chem. Rev. , vol.104 , pp. 17-117
    • Seco, J.M.1    Quinoa, E.2    Riguera, R.3
  • 13
    • 79951503684 scopus 로고    scopus 로고
    • For an excellent recent review of NMR methods used to determine absolute configuration that also covers chiral reagents for derivatization of less commonly encountered functional groups see:
    • Wenzel T.J., Chisholm C.D. Chirality 2011, 23:190-214. For an excellent recent review of NMR methods used to determine absolute configuration that also covers chiral reagents for derivatization of less commonly encountered functional groups see:.
    • (2011) Chirality , vol.23 , pp. 190-214
    • Wenzel, T.J.1    Chisholm, C.D.2
  • 32
    • 0035956411 scopus 로고    scopus 로고
    • For an excellent 'non-expert' account of how to use these types of CDA for determining the enantiomeric excess and absolute configuration of chiral amines, alcohols and carboxylic acids including simple experimental descriptions of how to carry out derivatisation experiments, see:
    • Seco J.M., Quinoa E., Riguera R. Tetrahedron: Asymmetry 2001, 12:2915-2925. For an excellent 'non-expert' account of how to use these types of CDA for determining the enantiomeric excess and absolute configuration of chiral amines, alcohols and carboxylic acids including simple experimental descriptions of how to carry out derivatisation experiments, see:.
    • (2001) Tetrahedron: Asymmetry , vol.12 , pp. 2915-2925
    • Seco, J.M.1    Quinoa, E.2    Riguera, R.3
  • 76
  • 150
    • 0028907528 scopus 로고
    • Phenylglycine dimethylamide is also a promising CDA for determining the enantiomer excess and absolute configuration of chiral carboxylic acids, see:
    • Nagai Y., Kusumi T. Tetrahedron Lett. 1995, 36:1853-1856. Phenylglycine dimethylamide is also a promising CDA for determining the enantiomer excess and absolute configuration of chiral carboxylic acids, see:.
    • (1995) Tetrahedron Lett. , vol.36 , pp. 1853-1856
    • Nagai, Y.1    Kusumi, T.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.