Chiral silylation reagents for the determination of absolute configuration by NMR spectroscopy

Organic Letters

Volumn 2, Issue 15, 2000, Pages 2381-2383

  Weibel, Douglas B ^a   Walker, Tameka R ^a   Schroeder, Frank C ^a   Meinwald, Jerrold ^a  

^a Department of Obstetrics Gynecology   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYL ALCOHOL; BIOLOGICAL FACTOR; ESTER; MACROLIDE; PROPANOL; SILOXANE;

ANIMAL; ARTICLE; CHEMISTRY; METABOLISM; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STEREOISOMERISM;

ANIMALS; BIOLOGICAL FACTORS; ESTERS; MACROLIDES; MAGNETIC RESONANCE SPECTROSCOPY; PROPANOLS; SILOXANES; STEREOISOMERISM;

EID: 0034720930     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol006162h     Document Type: Article

References (10)

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2. Dale, J. A.; Dull, D. L.; Mosher, H. S. J. Org. Chem. 1969, 34, 2543. Dale, J. A.; Mosher, H. S. J. Am. Chem. Soc. 1973, 95, 512.
3. Manuscript in preparation.
4. Alborn, H. T.; Turlings, T. C. J.; Jones, T. H.; Stenhagen, G.; Loughrin, J. H.; Tumlinson, J. H. Science 1997, 276, 945.
5. Pohnert G.; Koch, T.; Boland, W. Chem. Commun. 1999, 1087.
6. Clausen, R. P.; Bols, M. J. Org. Chem. 1997, 62, 4457.
7. Chan, T. H.; Peng, Q. J.; Wang, D.; Guo, J. A. J. Chem. Soc., Chem. Commun. 1987, 325.
8. +) m/z (rel intensity) 336 (3), 295 (24), 294 (98), 217 (100), 181 (33), 138 (49), 123 (52), 95 (86), 81 (89).
9. 4Si 644.4260, found 644.4252.
10. 2 pipet column provided siloxane 5 in nearly quantitative yield.