Double-decker phthalocyanine complex: Scanning tunneling microscopy study of film formation and spin properties

Progress in Surface Science

Volumn 89, Issue 2, 2014, Pages 127-160

  Komeda, Tadahiro ^a,b   Katoh, Keiichi ^a,b   Yamashita, Masahiro ^a,b  

^a TOHOKU UNIVERSITY   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

Atom manipulation; Au(111); Double decker phthalocyanine; Kondo resonance; Scanning tunneling microscope; Single molecule magnet

Indexed keywords

ATOMS; CHEMICAL BONDS; CHEMICAL MODIFICATION; DYES; ELECTRONIC STRUCTURE; FILMS; LIGANDS; MAGNETS; METALS; MOLECULES; NITROGEN COMPOUNDS; SCANNING TUNNELING MICROSCOPY; SPIN DYNAMICS; SURFACE MOUNT TECHNOLOGY;

ATOM MANIPULATION; AU(1 1 1 ); DOUBLE-DECKER PHTHALOCYANINE; KONDO RESONANCES; SINGLE-MOLECULE MAGNET;

SYNTHESIS (CHEMICAL);

EID: 84897415246     PISSN: 00796816     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.progsurf.2014.03.001     Document Type: Review

References (140)

1. C.C. Lenznoff, and A.B.P. Lever Phthalocyanines: Properties and Applications 1993 VCH New York
2. G. de la Torre, C.G. Claessens, and T. Torres Phthalocyanines: old dyes, new materials. Putting color in nanotechnology Chem. Commun. 20 2007 2000 2015 (Pubitemid 46964320)
3. N. Ishikawa, M. Sugita, T. Ishikawa, S. Koshihara, and Y. Kaizu Lanthanide double-decker complexes functioning as magnets at the single-molecular level J. Am. Chem. Soc. 125 2003 8694 8695 (Pubitemid 36886185)
4. N. Ishikawa, M. Sugita, N. Tanaka, T. Ishikawa, S.Y. Koshihara, and Y. Kaizu Upward temperature shift of the intrinsic phase lag of the magnetization of bis(phthalocyaninato)terbium by ligand oxidation creating an S = 1/2 spin Inorg. Chem. 43 2004 5498 5500
5. N. Ishikawa Single molecule magnet with single lanthanide ion Polyhedron 26 2007 2147 2153
6. S.A. Wolf, D.D. Awschalom, R.A. Buhrman, J.M. Daughton, S. von Molnar, M.L. Roukes, A.Y. Chtchelkanova, and D.M. Treger Spintronics: a spin-based electronics vision for the future Science 294 2001 1488 1495 (Pubitemid 33063913)
7. D. Gatteschi, and R. Sessoli Quantum tunneling of magnetization and related phenomena in molecular materials Angew. Chem. Int. Ed. 42 2003 268 297 (Pubitemid 36181508)
8. L. Bogani, and W. Wernsdorfer Molecular spintronics using single-molecule magnets Nat. Mater. 7 2008 179 186 (Pubitemid 351311291)
9. A.R. Rocha, V.M. Garcia-Suarez, S.W. Bailey, C.J. Lambert, J. Ferrer, and S. Sanvito Towards molecular spintronics Nat. Mater. 4 2005 335 339 (Pubitemid 40453812)
10. M. Irie Photochromism: memories and switches - introduction Chem. Rev. 100 2000 1683 1684
11. T. Yamase Photo- and electrochromism of polyoxometalates and related materials Chem. Rev. 98 1998 307 325 (Pubitemid 128633432)
12. R.G. Hicks Stable Radicals Fundamentals and Applied Aspects of Odd-Electron Compounds 2010 Wiley
13. G. Christou, D. Gatteschi, D.N. Hendrickson, and R. Sessoli Single-molecule magnets MRS Bull. 25 2000 66 71 (Pubitemid 32067218)
14. 12 single-molecule magnets as electron reservoirs with S > 10 ground states Angew. Chem. Int. Ed. 43 2004 6152 6156 (Pubitemid 39611883)
15. 12 nanomagnets on native and functionalized gold surfaces Adv. Mater. 17 2005 1612 1616 (Pubitemid 40963857)
16. 12 molecular magnets Phys. Rev. Lett. 96 2006 206801
17. D. Gatteschi, R. Sessoli, and A. Cornia Single-molecule magnets based on iron(III) oxo clusters Chem. Commun. 2000 725 732 (Pubitemid 30262296)
18. J.W. Buchler, and D.K.P. Ng K.M. Kadish, K.M. Smith, R. Guilard, The Porphyrin Handbook vol. 3 2000 Academic Press San Diego 245
19. F. Rosei, M. Schunack, Y. Naitoh, P. Jiang, A. Gourdon, E. Laegsgaard, I. Stensgaard, C. Joachim, and F. Besenbacher Properties of large organic molecules on metal surfaces Prog. Surf. Sci. 71 2003 95 146
20. J. Frommer Scanning tunneling microscopy and atomic force microscopy in organic chemistry Angew. Chem. Int. Ed. 31 1992 1298 1328
21. A.-S. Hallback, N. Oncel, N. Oncel, Jurriaan Huskens, H.J.W. Zandvliet, and B. Poelsema Inelastic electron tunneling spectroscopy on decanethiol at elevated temperatures Nano Lett. 4 2004 2393 2395 (Pubitemid 40002373)
22. T. Komeda, H. Isshiki, J. Liu, Y.-F. Zhang, N. Lorente, K. Katoh, B.K. Breedlove, and M. Yamashita Observation and electric current control of a local spin in a single-molecule magnet Nat. Commun. 2 2011 217
23. K. Katoh, Y. Yoshida, M. Yamashita, H. Miyasaka, B.K. Breedlove, T. Kajiwara, S. Takaishi, N. Ishikawa, H. Isshiki, Y.F. Zhang, T. Komeda, M. Yamagishi, and J. Takeya Direct observation of lanthanide(III)-phthalocyanine molecules on Au(111) by using scanning tunneling microscopy and scanning tunneling spectroscopy and thin-film field-effect transistor properties of Tb(III)- and Dy(III)-phthalocyanine molecules J. Am. Chem. Soc. 131 2009 9967 9976
24. T. Komeda, H. Isshiki, J. Liu, K. Katoh, M. Shirakata, B.K. Breedlove, and M. Yamashita Variation of Kondo peak observed in the assembly of heteroleptic 2,3-naphthalocyaninato phthalocyaninato Tb(III) double-decker complex on Au(111) ACS Nano 7 2013 1092 1099
25. 3OH Inorg. Chem. 24 1985 3162 3167
26. J.L. Paillaud, M. Drillon, A.D. Cian, J. Fischer, R. Weiss, and G. Villeneuve Phys. Rev. Lett. 67 1991 244 247
27. J.V. Barth, H. Brune, G. Ertl, and R.J. Behm Scanning tunneling microscopy observations on the reconstructed Au(111) surface - atomic-structure, long-range superstructure, rotational domains, and surface-defects Phys. Rev. B 42 1990 9307 9318
28. Y. Wang, N.S. Hush, and J.R. Reimers Simulation of the Au (111) - (22 × 3) surface reconstruction Phys. Rev. B 75 2007 233416
29. W. Chen, V. Madhavan, T. Jamneala, and M.F. Crommie Scanning tunneling microscopy observation of an electronic superlattice at the surface of clean gold Phys. Rev. Lett. 80 1998 1469
30. B. Min, A. Alemozafar, M. Biener, J. Biener, and C. Friend Reaction of Au(111) with sulfur and oxygen: scanning tunneling microscopic study Top. Catal. 36 2005 77 90
31. T. Komeda, H. Isshiki, and J. Liu Metal-free phthalocyanine (H2Pc) molecule adsorbed on the Au(111) surface: formation of a wide domain along a single lattice direction Sci. Technol. Adv. Mat. 11 2010 054602
32. Y.F. Zhang, H. Isshiki, K. Katoh, Y. Yoshida, M. Yamashita, H. Miyasaka, B.K. Breedlove, T. Kajiwara, S. Takaishi, and T. Komeda Low-temperature scanning tunneling microscopy investigation of bis(phthalocyaninato)yttrium growth on Au(111): from individual molecules to two-dimensional domains J. Phys. Chem. C 113 2009 9826 9830
33. Y.F. Zhang, H. Isshiki, K. Katoh, Y. Yoshida, M. Yamashita, H. Miyasaka, B.K. Breedlove, T. Kajiwara, S. Takaishi, and T. Komeda A low-temperature scanning tunneling microscope investigation of a nonplanar dysprosium- phthalocyanine adsorption on Au(111) J. Phys. Chem. C 113 2009 14407 14410
34. Y.F. Zhang, Y. Yang, Y. Kawazoe, and T. Komeda Experimental and theoretical investigations on the epitaxial growth of 4,4′ stilbenedicarboxylic acid molecules on Au(111) J. Phys. Chem. 131 2009 174706
35. H. Isshiki, J. Liu, K. Katoh, M. Yamashita, H. Miyasaka, B.K. Breedlove, S. Takaishi, and T. Komeda Scanning tunneling microscopy investigation of tris(phthalocyaninato)yttrium triple-decker molecules deposited on Au(111) J. Phys. Chem. C 114 2010 12202 12206
36. K. Katoh, T. Komeda, and M. Yamashita Surface morphologies, electronic structures, and Kondo effect of lanthanide(III)-phthalocyanine molecules on Au(111) by using STM, STS and FET properties for next generation devices Dalton Trans. 39 2010 4708 4723
37. K. Katoh, H. Isshiki, T. Komeda, and M. Yamashita Molecular spintronics based on single-molecule magnets composed of multiple-decker phthalocyaninato terbium(III) complex Chem. Asian J. 7 2012 1154 1169
38. R. Robles, N. Lorente, H. Isshiki, J. Liu, K. Katoh, B.K. Breedlove, M. Yamashita, and T. Komeda Spin doping of individual molecules by using single-atom manipulation Nano Lett. 12 2012 3609 3612
39. X. Lu, K.W. Hipps, X.D. Wang, and U. Mazur Scanning tunneling microscopy of metal phthalocyanines: d7 and d9 cases J. Am. Chem. Soc. 118 1996 7197
40. X. Lu, and K.W. Hipps Scanning tunneling microscopy of metal phthalocyanines: d6 and d8 cases J. Phys. Chem. B 101 1997 5391 5396 (Pubitemid 127581166)
41. I. Chizhov, G. Scoles, and A. Kahn The influence of steps on the orientation of copper phthalocyanine monolayers on Au(111) Langmuir 16 2000 4358
42. D.E. Barlow, and K.W. Hipps Scanning tunneling microscopy and spectroscopy study of vanadyl phthalocyanine on Au(111): the effect of oxygen binding and orbital mediated tunneling on the apparent corrugation J. Phys. Chem. B 104 2000 5993
43. K. Walzer, and M. Hietschold STM and STS investigation of ultrathin tin phthalocyanine layers adsorbed on HOPG(0001) and Au(111) Surf. Sci. 471 2001 1
44. D. Barlow, L. Scudiero, and K.W. Hipps Scanning tunneling microscopy of 1, 2, and 3 layers of electroactive compounds Ultramicroscopy 97 2003 47
45. M. Takada, and H. Tada Low temperature scanning tunneling microscopy of phthalocyanine multilayers on Au(111) surfaces Chem. Phys. Lett. 392 2004 265 269
46. Z.H. Cheng, L. Gao, Z.T. Deng, Q. Liu, N. Jiang, X. Lin, X.B. He, S.X. Du, and H.J. Gao Epitaxial growth of iron phthalocyanine at the initial stage on Au(111) surface J. Phys. Chem. C 111 2007 2656 2660 (Pubitemid 46774504)
47. M. Takada, and H. Tada Scanning tunneling microscopy and spectroscopy of phthalocyanine molecules on metal surfaces Jpn. J. Appl. Phys. Part 1 44 2005 5332 5335 (Pubitemid 43185953)
48. M. Takada, and H. Tada Direct observation of adsorption-induced electronic states by low-temperature scanning tunneling microscopy Ultramicroscopy 105 2005 22 25 (Pubitemid 41541934)
49. K. Nilson, J. Ahlund, B. Brena, E. Gothelid, J. Schiessling, N. Martensson, and C. Puglia Scanning tunneling microscopy study of metal-free phthalocyanine monolayer structures on graphite J. Phys. Chem. 127 2007 114702
50. G. Kresse, and J. Furthmuller Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Phys. Rev. B 54 1996 11169 11186
51. G. Kresse, and D. Joubert From ultrasoft pseudopotentials to the projector augmented-wave method Phys. Rev. B 59 1999 1758 1775
52. J.P. Perdew, K. Burke, and M. Ernzerhof Generalized gradient approximation made simple Phys. Rev. Lett. 77 1996 3865 3868 (Pubitemid 126631804)
53. S. Grimme, J. Antony, S. Ehrlich, and H. Krieg A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu J. Chem. Phys. 132 2010 154104
54. S. Grimme, J. Antony, T. Schwabe, and C. Muck-Lichtenfeld Density functional theory with dispersion corrections for supramolecular structures, aggregates, and complexes of (bio)organic molecules Org. Biomol. Chem. 5 2007 741 758
55. J. Tersoff, and D.R. Hamann Theory and application for the scanning tunneling microscope Phys. Rev. Lett. 50 1983 1998 2001
56. M.-L. Bocquet, H. Lesnard, S. Monturet, and N. Lorente R.A. van Santen, P. Sautet, Computational methods in catalysis and materials science 2009 Wiley-VCH Weinheim New York 201 ISBN 978-3-527-32032-5
57. L. Smykalla, P. Shukrynau, and M. Hietschold Investigation of ultrathin layers of bis(phthalocyaninato)lutetium(III) on graphite J. Phys. Chem. C 116 2012 8008 8013
58. R. Mason, G.A. Williams, and P.E. Fielding Structural chemistry of phthalocyaninato-cobalt(II) and manganese(II) J. Chem. Soc. Dalton Trans. 1234 1979 676 683
59. S. Heutz, S.M. Bayliss, R.L. Middleton, G. Rumbles, and T.S. Jones Polymorphism in phthalocyanine thin films: mechanism of the alfa to beta transition J. Phys. Chem. B 104 2000 7124 7129
60. A. Hoshino, Y. Takenaka, and H. Miyaji Redetermination of the crystal structure of α-copper phthalocyanine grown on KCl Acta Crystallogr. B 59 2003 393 403
61. K. Katoh, Y. Horii, N. Yasuda, W. Wernsdorfer, K. Toriumi, B.K. Breedlove, and M. Yamashita Multiple-decker phthalocyaninato dinuclear lanthanoid(III) single-molecule magnets with dual-magnetic relaxation processes Dalton Trans. 41 2013 13582 13600
62. 3 Eur. J. Inorg. Chem. 2000 2000 1771 1779
63. I. Chambrier, D.L. Hughes, J.C. Swarts, B. Isare, and M.J. Cook First example of a di-cadmium tris-phthalocyanine triple-decker sandwich complex Chem. Commun. 2006 3504 3506 (Pubitemid 44267663)
64. K. Katoh, T. Kajiwara, M. Nakano, Y. Nakazawa, W. Wernsdorfer, N. Ishikawa, B.K. Breedlove, and M. Yamashita Magnetic relaxation of single-molecule magnets in an external magnetic field: an ising dimer of a terbium(III)-phthalocyaninate triple-decker complex Chem. Eur. J. 17 2011 117 122
65. W. Deng, and K.W. Hipps Tip-sample distance dependence in the STM-based orbital-mediated tunneling spectrum of nickel(II) tetraphenylporphyrin deposited on Au(111) J. Phys. Chem. B 107 2003 10736 10740
66. A. Yazdani, D.M. Eigler, and N.D. Lang Off-resonance conduction through atomic wires Science 272 1996 1921 1924 (Pubitemid 26234498)
67. D. Gatteschi, R. Sessoli, and J. Villain Molecular Nanomagnets 2007 Oxford Univ. Press New York
68. A. Saywell, G. Magnano, C.J. Satterley, L.M.A. Perdigão, A.J. Britton, N. Taleb, M. del Carmen Giménez-López, N.R. Champness, J.N. O'Shea, and P.H. Beton Self-assembled aggregates formed by single-molecule magnets on a gold surface Nat. Commun. 1 2010 75
69. M. Mas-Torrent, N. Crivillers, V. Mugnaini, I. Ratera, C. Rovira, and J. Veciana Organic radicals on surfaces: towards molecular spintronics J. Mater. Chem. 19 2009 1691 1695
70. S. Heinze, M. Bode, A. Kubetzka, O. Pietzsch, X. Nie, S. Blugel, and R. Wiesendanger Real-space imaging of two-dimensional antiferromagnetism on the atomic scale Science 288 2000 1805 1808 (Pubitemid 30399014)
71. A. Wachowiak, J. Wiebe, M. Bode, O. Pietzsch, M. Morgenstern, and R. Wiesendanger Direct observation of internal spin structure of magnetic vortex cores Science 298 2002 577 580 (Pubitemid 35215307)
72. R. Wiesendanger, H.J. Güntherodt, G. Güntherodt, R.J. Gambino, and R. Ruf Observation of vacuum tunneling of spin-polarized electrons with the scanning tunneling microscope Phys. Rev. Lett. 65 1990 247 250
73. A.J. Heinrich, J.A. Gupta, C.P. Lutz, and D.M. Eigler Single-atom spin-flip spectroscopy Science 306 2004 466 469 (Pubitemid 39372441)
74. C.F. Hirjibehedin, C.P. Lutz, and A.J. Heinrich Spin coupling in engineered atomic structures Science 312 2006 1021 1024
75. N. Tsukahara, K.I. Noto, M. Ohara, S. Shiraki, N. Takagi, Y. Takata, J. Miyawaki, M. Taguchi, A. Chainani, S. Shin, and M. Kawai Adsorption-induced switching of magnetic anisotropy in a single iron(II) phthalocyanine molecule on an oxidized Cu(110) surface Phys. Rev. Lett. 102 2009 167203
76. N. Tsukahara, S. Shiraki, S. Itou, N. Ohta, N. Takagi, and M. Kawai Evolution of Kondo resonance from a single impurity molecule to the two-dimensional lattice Phys. Rev. Lett. 106 2011 187201
77. Y. Manassen, R.J. Hamers, J.E. Demuth, and A.J. Castellano Direct observation of the precession of individual paramagnetic spins on oxidized silicon surfaces Phys. Rev. Lett. 62 1989 2531 2534
78. Y. Manassen, E. Terovanesyan, D. Shachal, and S. Richter Electron-spin resonance-scanning tunneling microscopy experiments on thermally oxidized Si(111) Phys. Rev. B 48 1993 4887 4890
79. T. Komeda, and Y. Manassen Distribution of frequencies of a single precessing spin detected by scanning tunneling microscope Appl. Phys. Lett. 92 2008 212506
80. Y. Sainoo, H. Isshiki, S.M.F. Shahed, T. Takaoka, and T. Komeda Atomically resolved Larmor frequency detection on Si(111)-7x7 oxide surface Appl. Phys. Lett. 95 2009 082504
81. J. Kondo Effect of ordinary scattering on exchange scattering from magnetic impurity in metals Phys. Rev. 169 1968 437
82. V. Madhavan, W. Chen, T. Jamneala, M.F. Crommie, and N.S. Wingreen Tunneling into a single magnetic atom: spectroscopic evidence of the Kondo resonance Science 280 1998 567 569 (Pubitemid 28227755)
83. J.T. Li, W.D. Schneider, R. Berndt, and B. Delley Kondo scattering observed at a single magnetic impurity Phys. Rev. Lett. 80 1998 2893 2896 (Pubitemid 128621689)
84. H.C. Manoharan, C.P. Lutz, and D.M. Eigler Quantum mirages formed by coherent projection of electronic structure Nature 403 2000 512 515 (Pubitemid 30082189)
85. N. Knorr, M.A. Schneider, L. Diekhoer, P. Wahl, and K. Kern Kondo effect of single co Adatoms on Cu surfaces Phys. Rev. Lett. 88 2002 096804
86. P. Wahl, L. Diekhoner, G. Wittich, L. Vitali, M.A. Schneider, and K. Kern Kondo effect of molecular complexes at surfaces: ligand control of the local spin coupling Phys. Rev. Lett. 95 2005 166601
87. N. Neel, J. Kroger, L. Limot, K. Palotas, W.A. Hofer, and R. Berndt Conductance and Kondo effect in a controlled single-atom contact Phys. Rev. Lett. 98 2007 016801
88. A.D. Zhao, Q.X. Li, L. Chen, H.J. Xiang, W.H. Wang, S. Pan, B. Wang, X.D. Xiao, J.L. Yang, J.G. Hou, and Q.S. Zhu Controlling the Kondo effect of an adsorbed magnetic ion through its chemical bonding Science 309 2005 1542 1544 (Pubitemid 41266476)
89. V. Iancu, A. Deshpande, and S.W. Hla Manipulation of the Kondo effect via two-dimensional molecular assembly Phys. Rev. Lett. 97 2006 266603
90. L. Chen, Z.P. Hu, A.D. Zhao, B. Wang, Y. Luo, J.L. Yang, and J.G. Hou Mechanism for negative differential resistance in molecular electronic devices: local orbital symmetry matching Phys. Rev. Lett. 99 2007 146803
91. P. Jarillo-Herrero, J. Kong, H.S.J. van der Zant, C. Dekker, L.P. Kouwenhoven, and S. De Franceschi Orbital Kondo effect in carbon nanotubes Nature 434 2005 484 488 (Pubitemid 40480980)
92. I. Fernandez-Torrente, K.J. Franke, and J.I. Pascual Vibrational Kondo effect in pure organic charge-transfer assemblies Phys. Rev. Lett. 101 2008 217203
93. H. Jeong, A.M. Chang, and M.R. Melloch The Kondo effect in an artificial quantum dot molecule Science 293 2001 2221 2223 (Pubitemid 32900224)
94. J. Liu, H. Isshiki, K. Katoh, T. Morita, B.K. Breedlove, M. Yamashita, and T. Komeda First observation of a kondo resonance for a stable neutral pure organic radical, 1,3,5-triphenyl-6-oxoverdazyl, adsorbed on the Au(111) surface J. Am. Chem. Soc. 135 2013 651 658
95. S. Müllegger, M. Rashidi, M. Fattinger, and R. Koch Surface-supported hydrocarbon Pi radicals show Kondo behavior J. Phys. Chem. C 117 2013 5718 5721
96. L. Gao, W. Ji, Y.B. Hu, Z.H. Cheng, Z.T. Deng, Q. Liu, N. Jiang, X. Lin, W. Guo, S.X. Du, W.A. Hofer, X.C. Xie, and H.J. Gao Site-specific Kondo effect at ambient temperatures in iron-based molecules Phys. Rev. Lett. 99 2007 106402
97. E. Minamitani, N. Tsukahara, D. Matsunaka, Y. Kim, N. Takagi, and M. Kawai Symmetry-driven novel Kondo effect in a molecule Phys. Rev. Lett. 109 2012
98. K. Nagaoka, T. Jamneala, M. Grobis, and M.F. Crommie Temperature dependence of a single Kondo impurity Phys. Rev. Lett. 88 2002 077205
99. Y. Meir, N.S. Wingreen, and P.A. Lee Low-temperature transport through a quantum dot: the Anderson model out of equilibrium Phys. Rev. Lett. 70 1993 2601 2604
100. J. Park, A.N. Pasupathy, J.I. Goldsmith, C. Chang, Y. Yaish, J.R. Petta, M. Rinkoski, J.P. Sethna, H.D. Abruna, P.L. McEuen, and D.C. Ralph Coulomb blockade and the Kondo effect in single-atom transistors Nature 417 2002 722 725 (Pubitemid 34649374)
101. P. Schlottmann Some exact results for dilute mixed-valent and heavy-fermion systems Phys. Rep. Rev. Sec. Phys. Lett. 181 1989 1 119
102. A.C. Hewson The Kondo Problem to Heavy Fermions 1993 Cambridge University Press London
103. J.M. Auerhammer, M. Knupfer, H. Peisert, and J. Fink The copper phthalocyanine/Au(100) interface studied using high resolution electron energy-loss spectroscopy Surf. Sci. 506 2002 333 338 (Pubitemid 34515014)
104. T. Komeda Chemical identification and manipulation of molecules by vibrational excitation via inelastic tunneling process with scanning tunneling microscopy Prog. Surf. Sci. 78 2005 41 85 (Pubitemid 41101239)
105. U. Fano Effects of configuration interaction on intensities and phase shifts Phys. Rev. 124 1961 1866 1878
106. O. Ujsaghy, J. Kroha, L. Szunyogh, and A. Zawadowski Theory of the Fano resonance in the STM tunneling density of states due to a single Kondo impurity Phys. Rev. Lett. 85 2000 2557 2560
107. M. Plihal, and J.W. Gadzuk Nonequilibrium theory of scanning tunneling spectroscopy via adsorbate resonances: nonmagnetic and Kondo impurities Phys. Rev. B 63 2001 085404
108. A. DiLullo, S.-H. Chang, N. Baadji, K. Clark, J.-P. Klöckner, M.-H. Prosenc, S. Sanvito, R. Wiesendanger, G. Hoffmann, and S.-W. Hla Molecular Kondo chain Nano Lett. 12 2012 3174 3179
109. V. Iancu, A. Deshpande, and S.W. Hla Manipulating Kondo temperature via single molecule switching Nano Lett. 6 2006 820 823
110. J.M. Aguiar-Hualde, G. Chiappe, E. Louis, E.V. Anda, and J. Simonin Kondo resonance in the conductance of CoPc/Au(111) and TBrPP-Co/Cu(111) Phys. Rev. B 79 2009 155415
111. J.M. Aguiar-Hualde, G. Chiappe, E. Louis, E.V. Anda, and J. Simonin Modeling the effects of molecule distortion on the Kondo resonance in the conductance of CoPc/Au(111) and TBrPP-Co/Cu(111) Phys. Status Solidi A 206 2009 2217 2227
112. J.M. Aguiar-Hualde, G. Chiappe, E. Louis, and E.V. Anda Kondo effect in transport through molecules adsorbed on metal surfaces: from Fano dips to Kondo peaks Phys. Rev. B 76 2007
113. J.P. Sauvage Transition metal-containing rotaxanes and catenanes in motion: toward molecular machines and motors Acc. Chem. Res. 31 1998 611 619
114. J.C. Medina, C. Li, S.G. Bott, J.L. Atwood, and G.W. Gokel A molecular receptor based on the ferrocene system: selective complexation using atomic ball bearings J. Am. Chem. Soc. 113 1991 366 367
115. P.L. Anelli, N. Spencer, and J.F. Stoddart A molecular shuttle J. Am. Chem. Soc. 113 1991 5131 5133
116. H. Murakami, A. Kawabuchi, K. Kotoo, M. Kunitake, and N. Nakashima A light-driven molecular shuttle based on a rotaxane J. Am. Chem. Soc. 119 1997 7605 7606 (Pubitemid 27355137)
117. K. Tashiro, K. Konishi, and T. Aida Metal bisporphyrinate double-decker complexes as redox-responsive rotating modules. Studies on ligand rotation activities of the reduced and oxidized forms using chirality as a probe J. Am. Chem. Soc. 122 2000 7921 7926 (Pubitemid 30659413)
118. L. Bartels, G. Meyer, K.H. Rieder, D. Velic, E. Knoesel, A. Hotzel, M. Wolf, and G. Ertl Dynamics of electron-induced manipulation of individual CO molecules on Cu(III) Phys. Rev. Lett. 80 1998 2004 2007 (Pubitemid 128623050)
119. T. Komeda, Y. Kim, M. Kawai, B.N.J. Persson, and H. Ueba Lateral hopping of molecules induced by excitation of internal vibration mode Science 295 2002 2055 2058 (Pubitemid 34229462)
120. T. Komeda, S. Morita, S. Tanaka, H. Yamada, and S. Morita Roadmap of Scanning Probe Microscopy S. Morita, Springer 2007 Berlin Heidelberg 85 94
121. H. Tanaka, T. Ikeda, M. Takeuchi, K. Sada, S. Shinkai, and T. Kawai Molecular rotation in self-assembled multidecker porphyrin complexes ACS Nano 5 2011 9575 9582
122. Y.-S. Fu, J. Schwöbel, S.-W. Hla, A. Dilullo, G. Hoffmann, S. Klyatskaya, M. Ruben, and R. Wiesendanger Reversible chiral switching of bis(phthalocyaninato) terbium(III) on a metal surface Nano Lett. 12 2012 3931 3935
123. T. Huang, J. Zhao, M. Feng, A.A. Popov, S. Yang, L. Dunsch, and H. Petek A molecular switch based on current-driven rotation of an encapsulated cluster within a fullerene cage Nano Lett. 11 2011 5327 5332
124. D. Tanaka, T. Inose, H. Tanaka, S. Lee, N. Ishikawa, and T. Ogawa Proton-induced switching of the single molecule magnetic properties of a porphyrin based Tb-III double-decker complex Chem. Commun. 48 2012 7796 7798
125. J. Kido, K. Hongawa, K. Okuyama, and K. Nagai White light-emitting organic electroluminescent devices using the poly(N-vinylcarbazole) emitter layer doped with three fluorescent dyes Appl. Phys. Lett. 64 1994 815 817
126. Y.L. Gao, and L. Yan Cs doping and energy level shift in CuPc Chem. Phys. Lett. 380 2003 451 455
127. L. Yan, N.J. Watkins, S. Zorba, Y. Gao, and C.W. Tang Direct observation of Fermi-level pinning in Cs-doped CuPc film Appl. Phys. Lett. 79 2001 4148 4150
128. R.F.W. Bader Atoms in Molecules: A Quantum Theory 1990 Oxford University Press New York
129. H.J. Ding, and Y.L. Gao Electronic structure of Cs-doped tris(8-hydroxyquinoline) aluminum Appl. Phys. Lett. 86 2005 213508
130. H.J. Ding, K.W. Park, K. Green, and Y.L. Gao Electronic structure modification of copper phthalocyanine (CuPc) induced by intensive Na doping Chem. Phys. Lett. 454 2008 229 232
131. H.J. Ding, and Y.L. Gao Evolution of the unoccupied states in Cs-doped copper phthalocyanine Appl. Phys. Lett. 92 2008 053309
132. A. Dodabalapur, L. Torsi, and H.E. Katz Organic transistors: two-dimensional transport and improved electrical characteristics Science 268 1995 270 271
133. C. Rost, D.J. Gundlach, S. Karg, and W. Rieß Ambipolar organic field-effect transistor based on an organic heterostructure J. Appl. Phys. 95 2004 5782 5787
134. R.W.I. De Boer, A.F. Stassen, M.F. Craciun, C.L. Mulder, A. Molinari, S. Rogge, and A.F. Morpurgo Ambipolar Cu- and Fe-phthalocyanine single-crystal field-effect transistors Appl. Phys. Lett. 86 2005 1 3
135. T. Yasuda, and T. Tsutsui Organic field-effect transistors based on high electron and ambipolar carrier transport properties of copper-phthalocyanine Chem. Phys. Lett. 402 2005 395 398 (Pubitemid 40126608)
136. Z. Bao, A.J. Lovinger, and A. Dodabalapur Organic field-effect transistors with high mobility based on copper phthalocyanine Appl. Phys. Lett. 69 1996 3066 3068 (Pubitemid 126593031)
137. J. Takeya, C. Goldmann, S. Haas, K.P. Pernstich, B. Ketterer, and B. Batlogg Field-induced charge transport at the surface of pentacene single crystals: a method to study charge dynamics of two-dimensional electron systems in organic crystals J. Appl. Phys. 94 2003 5800 5804
138. M. Urdampilleta, S. Klyatskaya, J.P. Cleuziou, M. Ruben, and W. Wernsdorfer Supramolecular spin valves Nat. Mater. 10 2011 502 506
139. A. Candini, S. Klyatskaya, M. Ruben, W. Wernsdorfer, and M. Affronte Graphene spintronic devices with molecular nanomagnets Nano Lett. 11 2011 2634 2639
140. R. Vincent, S. Klyatskaya, M. Ruben, W. Wernsdorfer, and F. Balestro Electronic read-out of a single nuclear spin using a molecular spin transistor Nature 488 2012 357 360