Chemical identification and manipulation of molecules by vibrational excitation via inelastic tunneling process with scanning tunneling microscopy

Progress in Surface Science

Volumn 78, Issue 2, 2005, Pages 41-85

  Komeda, Tadahiro ^a,b  

^a TOHOKU UNIVERSITY   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

Atom manipulation; DIET; DIMET; IETS; Inelastic tunneling; Inelastic tunneling spectroscopy; Molecular rotation; Selection rule; Single molecule spectroscopy; Site selective chemistry; STM; Surface migration; Vibration excitation; Vibration spectroscopy

Indexed keywords

CHARACTERIZATION; HIGH RESOLUTION ELECTRON MICROSCOPY; MOLECULES; NEGATIVE IONS; RESEARCH AND DEVELOPMENT MANAGEMENT; SCANNING TUNNELING MICROSCOPY;

ADSORBATES; ELECTRON ENERGY; VIBRATIONAL EXCITATIONS;

MOLECULAR VIBRATIONS;

EID: 23344445271     PISSN: 00796816     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.progsurf.2005.05.001     Document Type: Review

References (112)

1. J.K. Gimzewski, and C. Joachim Nanoscale science of single molecules using local probes Science 283 1999 1683 1688
2. J.G. Simmons Generalized formula for the electric tunnel effect between similar electrodes separated by a thin insulating film J. Appl. Phys. 24 1963 1793 1803
3. R.H. Fowler, and L. Nordheim Electron emission in intense electric field Proc. R. Soc. London A 119 1928 173 181
4. R.S. Becker, J.A. Golovchenko, and B.S. Swartzentruber Electron interferometry at crystal-surfaces Phys. Rev. Lett. 55 1985 987 990
5. A.J. Caamano, Y. Pogorelov, O. Custance, J. Mendez, A.M. Baro, J.Y. Veuillen, J.M. Gomez-Rodriguez, and J.J. Saenz Field emission interferometry with the scanning tunneling microscope Surf. Sci. 426 1999 L420 L425
6. K. Bobrov, A.J. Mayne, and G. Dujardin Atomic-scale imaging of insulating diamond through resonant electron injection Nature 413 2001 616 619
7. U. Durig, J.K. Gimzewski, and D.W. Pohl Experimental observation of forces acting during scanning tunneling microscopy Phys. Rev. Lett. 57 1986 2403 2406
8. U. Durig, O. Zuger, and D.W. Pohl Force sensing in scanning tunnelling microscopy: observation of adhesion forces on clean metal surfaces J. Microsc. 152 1988 259 267
9. U. Durig, O. Zuger, and D.W. Pohl Observation of metallic adhesion using the scanning tunneling microscope Phys. Rev. Lett. 65 1990 349 352
10. G. Binnig, N. Garcia, and H. Rohrer Conductivity sensitivity of inelastic scanning tunneling microscopy Phys. Rev. B 32 1985 1336 1338
11. H. Ibach, and D.L. Mills Electron Energy Loss Spectroscopy and Surface Vibrations 1982 Academic Press London
12. D. Sokcevic, Z. Lenac, R. Brako, and M. Sunjic Excitation of adsorbed molecule vibrations in low energy electron scattering Z. Phys. B 28 1977 273 281
13. C.H. Li, S.Y. Tong, and D.L. Mills Large-angle inelastic electron-scattering from adsorbate vibrations-basic theory Phys. Rev. B 21 1980 3057 3073
14. G.J. Schulz Resonances in electron impact on diatomic molecules Rev. Mod. Phys. 45 1973 423 486
15. 2 by electron impact above 4 eV Phys. Rev. Lett. 31 1973 969 972
16. F.J. Himpsel, and T. Fauster Empty orbitals of adsorbates determined by inverse ultraviolet photoemission Phys. Rev. Lett. 49 1982 1583 1586
17. J. Rogozik, H. Scheidt, V. Dose, K.C. Prince, and A.M. Bradshaw The 2-pi-derived level in the adsorption system Co/Cu(1 1 0) Surf. Sci. 145 1984 L481 L487
18. 2 adsorbed on a silver surface Phys. Rev. Lett. 47 1981 1166 1169
19. L. Esaki New phenomenon in narrow germanium p-n junctions Phys. Rev. 109 1958 603 604
20. R.C. Jaklevic, and J. Lambe Molecular vibration spectra by electron tunneling Phys. Rev. Lett. 17 1966 1139 1140
21. P.K. Hansma Tunneling Spectroscopy 1982 Plenum Press New York
22. D.G. Walmsley, and J.L. Tomlin Prog. Surf. Sci. 18 1985 247 447
23. U. Mazur, and K.W. Hipps J. Chalmers P. Griffiths Handbook of Vibrational Spectroscopy vol. 1 2002 John Wiley and Sons New York 812 829
24. T. Komeda, Y. Kim, and M. Kawai Imaging an isolated molecule on metal: STM images of CO on Pd(1 1 0) and electronic configuration near the Fermi level Riken Rev. 2001 26 33
25. J. Kirtley, and P. Soven Multiple-scattering theory of intensities in inelastic-electron-tunneling spectroscopy Phys. Rev. B 19 1979 1812 1817
26. B.N.J. Persson, and J.E. Demuth Inelastic electron tunnelling from a metal tip Solid State Commun. 57 1986 769 772
27. B.N.J. Persson Inelastic vacuum tunneling Phys. Scr. (Sweden) 38 1988 282 290
28. A. Bayman, P.K. Hansma, and W.C. Kaska Shifts and dips in inelastic-electron-tunneling spectra due to the tunnel-junction environment Phys. Rev. B 24 1981 2449 2455
29. R.J. Hamers, and J.E. Demuth Electronic structure of localized Si dangling-bond defects by tunneling spectroscopy Phys. Rev. Lett. 60 1988 2527 2530
30. E.J. van Loenen, J.E. Demuth, R.M. Tromp, and R.J. Hamers Local electron states and surface geometry of Si(1 1 1)-Ag Phys. Rev. Lett. 58 1987 373 376
31. R.M. Feenstra Scanning tunneling spectroscopy Surf. Sci. 300 1994 965 979
32. R.M. Feenstra Tunneling spectroscopy of the (1 1 0)-surface of direct-gap III-V semiconductors Phys. Rev. B 50 1994 4561 4570
33. R.M. Feenstra, D.A. Collins, D.Z.Y. Ting, M.W. Wang, and T.C. McGill Interface roughness and asymmetry in InAs/GaSb superlattices studied by scanning-tunneling-microscopy Phys. Rev. Lett. 72 1994 2749 2752
34. L.J. Lauhon, and W. Ho Effects of temperature and other experimental variables on single molecule vibrational spectroscopy with the scanning tunneling microscope Rev. Sci. Instrum. 72 2001 216 223
35. B.C. Stipe, M.A. Rezaei, and W. Ho A variable-temperature scanning tunneling microscope capable of single-molecule vibrational spectroscopy Rev. Sci. Instrum. 70 1999 137 143
36. Y. Sainoo, Y. Kim, T. Komeda, and M. Kawai Inelastic tunneling spectroscopy using scanning tunneling microscopy on trans-2-butene molecule: Spectroscopy and mapping of vibrational feature J. Chem. Phys. 120 2004 7249 7251
37. A. Baratoff, and B.N.J. Persson Theory of the local tunneling spectrum of a vibrating adsorbate J. Vac. Sci. Technol. A 6 1988 331 335
38. B.C. Stipe, M.A. Rezaei, and W. Ho Single-molecule vibrational spectroscopy and microscopy Science 280 1998 1732 1735
39. 2 with silane modified alumina Surf. Sci. 207 1989 385 400
40. L.J. Lauhon, and W. Ho Single-molecule vibrational spectroscopy and microscopy: CO on Cu(0 0 1) and Cu(1 1 0) Phys. Rev. B 60 1999 R8525 R8528
41. M. Headgordon, and J.C. Tully Molecular-orbital calculations of the lifetimes of the vibrational-modes of CO on Cu(1 0 0) Phys. Rev. B 46 1992 1853 1856
42. M. Morin, N.J. Levinos, and A.L. Harris Vibrational energy transfer of CO/Cu(1 0 0): nonadiabatic vibration/electron coupling J. Chem. Phys. 96 1992 3950 3956
43. C.J. Hirschmugl, G.P. Williams, F.M. Hoffmann, and Y.J. Chabal Adsorbate-substrate resonant interactions observed for Co on Cu(1 0 0) in the far infrared Phys. Rev. Lett. 65 1990 480 483
44. B.N.J. Persson Surface resistivity and vibrational damping in adsorbed layers Phys. Rev. B 44 1991 3277 3296
45. R. Ryberg The metal-molecule stretch vibrational mode studied by infrared spectroscopy; CO on Pt(1 1 1) J. Electron Spectrosc. Relat. Phenom. 54-55 1990 65 80
46. L.J. Lauhon, and W. Ho Single-molecule chemistry and vibrational spectroscopy: pyridine and benzene on Cu(0 0 1) J. Phys. Chem. A 104 2000 2463 2467
47. N. Lorente, M. Persson, L.J. Lauhon, and W. Ho Symmetry selection rules for vibrationally inelastic tunneling Phys. Rev. Lett. 86 2001 2593 2596
48. N. Mingo, and K. Makoshi Calculation of the inelastic scanning tunneling image of acetylene on Cu(1 0 0) Phys. Rev. Lett. 84 2000 3694 3697
49. B.N.J. Persson, and A. Baratoff Inelastic electron tunneling from a metal tip: the contribution from resonant processes Phys. Rev. Lett. 59 1987 339
50. T. Mii, S. Tikhodeev, and H. Ueba Theory of vibrational tunneling spectroscopy of adsorbates on metal surfaces Surf. Sci. 502 2002 26 33
51. T. Mii, S.G. Tikhodeev, and H. Ueba Spectral features of inelastic electron transport via a localized state Phys. Rev. B 68 2003 205406 205410
52. Y. Kim, T. Komeda, and M. Kawai Single-molecule reaction and characterization by vibrational excitation Phys. Rev. Lett. 89 2002 126104 126107
53. B.C. Stipe, M.A. Rezaei, and W. Ho Coupling of vibrational excitation to the rotational motion of a single adsorbed molecule Phys. Rev. Lett. 81 1998 1263 1266
54. J.R. Hahn, H.J. Lee, and W. Ho Electronic resonance and symmetry in single-molecule inelastic electron tunneling Phys. Rev. Lett. 85 2000 1914 1917
55. J.I. Pascual, J.J. Jackiw, Z. Song, P.S. Weiss, H. Conrad, and H.P. Rust Adsorbate-substrate vibrational modes of benzene on Ag(1 1 0) resolved with scanning tunneling spectroscopy Phys. Rev. Lett. 86 2001 1050 1053
56. N. Lorente, and M. Persson Theory of single molecule vibrational spectroscopy and microscopy Phys. Rev. Lett. 85 2000 2997 3000
57. N.H. Tolk, M.M. Traum, J.C. Tully, and T.E. Madey Desorption Induced by Electronic Transition, DIET I 1983 Springer Berlin
58. R.D. Ramsier, and J.T. Yates Electron-stimulated desorption-principles and applications Surf. Sci. Rep. 12 1991 243 378
59. P.A. Redhead Interaction of slow electrons with chemisorbed oxygen Can. J. Phys. 42 1964 886 905
60. D. Menzel, and R. Gomer Desorption from metal surfaces by low-energy electrons J. Chem. Phys. 41 1964 3311 3328
61. J.W. Gadzuk Resonance-assisted hot-electron-induced desorption Surf. Sci. 342 1995 345 358
62. A. Hoffman, X. Guo, J.T. Yates Jr., J.W. Gadzuk, and C.W. Clark Electron-stimulated desorption and surface species conversion: the observation of a desorption resonance for atomic oxygen on the Pd(1 1 1) surface J. Chem. Phys. 90 1989 5793 5800
63. J.W. Gadzuk, and C.W. Clark Resonance enhanced electron stimulated desorption J. Chem. Phys. 91 1989 3174 3181
64. J.A. Misewich, T.F. Heinz, and D.M. Newns Desorption induced by multiple electronic-transitions Phys. Rev. Lett. 68 1992 3737 3740
65. J.A. Prybyla, T.F. Heinz, J.A. Misewich, M.M.T. Loy, and J.H. Glownia Desorption induced by femtosecond laser pulses Phys. Rev. Lett. 64 1990 1537 1540
66. S.W. Gao, B.I. Lundqvist, and W. Ho Hot-electron-induced vibrational heating at surface-importance of a quantum-mechanical description Surf. Sci. 341 1995 L1031 L1036
67. F.J. Kao, D.G. Busch, D. Cohen, D.G. Dacosta, and W. Ho Femtosecond laser-desorption of molecularly adsorbed oxygen from Pt(1 1 1) Phys. Rev. Lett. 71 1993 2094 2097
68. 2 + CO on Pt(1 1 1) at 80-K Phys. Rev. Lett. 70 1993 4098 4101
69. J.W. Gadzuk Inelastic resonance scattering, tunneling, and desorption Phys. Rev. B 44 1991 13466 13477
70. D. Mocuta, J. Ahner, and J.T. Yates Adsorption and electron-stimulated dissociation of ammonia on Cu(1 1 0): an ESDIAD study Surf. Sci. 383 1997 299 307
71. 5Cl on Ag(1 1 1)-electron-energy dependence Chem. Phys. Lett. 198 1992 615 620
72. M. Kawai, T. Komeda, Y. Kim, Y. Sainoo, and S. Katano Single-molecule reactions and spectroscopy via vibrational excitation Phil. Trans. R. Soc. Lond. A 362 2004 1163 1171
73. R.S. Becker, G.S. Higashi, Y.J. Chabal, and A.J. Becker Atomic scale conversion of clean Si(1 1 1):H-1 × 1 to Si(1 1 1)-2 × 1 by electron-stimulated desorption Phys. Rev. Lett. 65 1990 1917 1920
74. T.C. Shen, C. Wang, G.C. Abeln, J.R. Tucker, J.W. Lyding, P. Avouris, and R.E. Walkup Atomic-scale desorption through electronic and vibrational excitation mechanisms Science 268 1995 1590 1592
75. P. Avouris, R.E. Walkup, A.R. Rossi, T.C. Shen, G.C. Abeln, J.R. Tucker, and J.W. Lyding STM-induced H atom desorption from Si(1 0 0): isotope effects and site selectivity Chem. Phys. Lett. 257 1996 148 154
76. T.C. Shen, and P. Avouris Electron stimulated desorption induced by the scanning tunneling microscope Surf. Sci. 390 1997 35 44
77. J.W. Lyding, K. Hess, G.C. Abeln, D.S. Thompson, J.S. Moore, M.C. Hersam, E.T. Foley, J. Lee, Z. Chen, S.T. Hwang, H. Choi, P. Avouris, and I.C. Kizilyalli Ultrahigh vacuum-scanning tunneling microscopy nanofabrication and hydrogen/deuterium desorption from silicon surfaces: implications for complementary metal oxide semiconductor technology Appl. Surf. Sci. 132 1998 221 230
78. B.N.J. Persson, and P. Avouris Local bond breaking via STM-induced excitations: the role of temperature Surf. Sci. 390 1997 45 54
79. L. Bartels, G. Meyer, K.H. Rieder, D. Velic, E. Knoesel, A. Hotzel, M. Wolf, and G. Ertl Dynamics of electron-induced manipulation of individual CO molecules on Cu(III) Phys. Rev. Lett. 80 1998 2004 2007
80. T. Komeda, Y. Kim, Y. Fujita, Y. Sainoo, and M. Kawai Local chemical reaction of benzene on Cu(1 1 0) via STM-induced excitation J. Chem. Phys. 120 2004 5347 5352
81. Q. Chen, B.G. Frederick, C.C. Perry, A.W. Munz, T. Bertrams, and N.V. Richardson Negative ion mediated electron stimulated disordering of c(8 × 2) benzoate-Cu(1 1 0): extension of the displaced harmonic oscillator model Surf. Sci. 390 1997 55 62
82. D.R. Huntley, S.L. Jordan, and F.A. Grimm Adsorption and thermal decomposition of benzene on Ni(1 1 0) studied by chemical, spectroscopic, and computational methods J. Phys. Chem. 96 1992 1409 1417
83. K. Stokbro, C. Thirstrup, M. Sakurai, U. Quaade, B.Y.K. Hu, F. Perez-Murano, and F. Grey STM-induced hydrogen desorption via a hole resonance Phys. Rev. Lett. 80 1998 2618 2621
84. D.M. Eigler, C.P. Lutz, and W.E. Rudge An atomic switch realized with the scanning tunneling microscope Nature 352 1991 600 603
85. R.E. Walkup, D.M. Newns, and P. Avouris Role of multiple inelastic transitions in atom-transfer with the scanning tunneling microscope Phys. Rev. B 48 1993 1858 1861
86. B.N.J. Persson, and A. Baratoff Inelastic electron tunneling from a metal tip: the contribution from resonant processes Phys. Rev. Lett. 59 1987 339 342
87. A.G. Fedorus, V.V. Gonchar, O.V. Kanash, E.V. Klimenko, A.G. Naumovets, and I.N. Zasimovich Electron-stimulated disordering in adsorbed layers Surf. Sci. 251 1991 846 850
88. H.J. Jansch, J. Xu, and J.T. Yates Jr. Electron stimulated surface migration of CO on Pt(3 3 5). First spectroscopic evidence for a new phenomenon J. Chem. Phys. 99 1993 721 724
89. B.G. Briner, M. Doering, H.P. Rust, and A.M. Bradshaw Microscopic molecular diffusion enhanced by adsorbate interactions Science 278 1997 257 260
90. T. Komeda, Y. Kim, and M. Kawai Lateral motion of adsorbate induced by vibrational mode excitation with inelastic tunneling electron Surf. Sci. 502-503 2002 12 17
91. E. Schweizer, B.N.J. Persson, M. Tushaus, D. Hoge, and A.M. Bradshaw The potential energy surface, vibrational phase relaxation and the order-disorder transition in the adsorption system Pt(1 1 1)-CO Surf. Sci. 213 1989 49 89
92. J. Ellis, J.P. Toennies, and G. Witte Helium atom scattering study of the frustrated translation mode of CO adsorbed on the Cu(0 0 1) surface J. Chem. Phys. 102 1995 5059 5070
93. T. Komeda, Y. Kim, M. Kawai, B.N.J. Persson, and H. Ueba Lateral hopping of molecules induced by excitation of internal vibration mode Science 295 2002 2055 2058
94. R. Raval, S. Haq, M.A. Harrison, G. Blyholder, and D.A. King Molecular adsorbate-induced surface reconstruction: CO/Pd(1 1 0) Chem. Phys. Lett. 167 1990 391 398
95. H. Kato, M. Kawai, and J. Yoshinobu Switching in the molecular orientation ruled by steric repulsion of adsorbed CO on Pd(1 1 0) Phys. Rev. Lett. 82 1999 1899 1902
96. B.N.J. Persson, and M. Persson Vibrational lifetime for CO adsorbed on Cu(1 0 0) Solid State Commun. 36 1980 175 179
97. R. Ryberg Vibrational phase relaxation of the metal-molecule stretch mode-CO on Pt(1 1 1) Phys. Rev. B 40 1989 8567 8569
98. M. Trenary, K.J. Uram, F. Bozso, and J.T. Yates Jr. Temperature dependence of the vibrational lineshape of CO chemisorbed on the Ni(1 1 1) surface Surf. Sci. 146 1984 269 280
99. T.A. Germer, J.C. Stephenson, E.J. Heilweil, and R.R. Cavanagh Picosecond time-resolved adsorbate response to substrate heating: spectroscopy and dynamics of CO/Cu(1 0 0) J. Chem. Phys. 101 1994 1704 1716
100. B.N.J. Persson, and H. Ueba Theory of inelastic tunneling induced motion of adsorbates on metal surfaces Surf. Sci. 502 2002 18 25
101. L.J. Lauhon, and W. Ho Single molecule thermal rotation and diffusion: acetylene on Cu(0 0 1) J. Chem. Phys. 111 1999 5633 5636
102. Y. Sainoo, Y. Kim, H. Fukidome, T. Komeda, M. Kawai, and H. Shigekawa Characteristic configuration of cis-2-butene molecule on Pd(1 1 0) determined by scanning tunneling microscopy Jpn. J. Appl. Phys. 41 2002 4976 4979
103. Y. Sainoo, Y. Kim, T. Komeda, M. Kawai, and H. Shigekawa Observation of cis-2-butene molecule on Pd(1 1 0) by cryogenic STM: site determination using tunneling-current-induced rotation Surf. Sci. 536 2003 L403 L407
104. Y. Sainoo, Y. Kim, T. Okawa, T. Komeda, H. Shigekawa, M. Kawai, Excitation of molecular vibration modes in STM inelastic process: Examination through action spectra of cis-2-Butene on Pd(1 1 0), Phys. Rev. Lett., to appear.
105. J.I. Pascual, N. Lorente, Z. Song, H. Conrad, and H.-P. Rust Selectivity in vibrationally mediated single-molecule chemistry Nature 423 2003 525 528
106. H. Ueba, and B.N.J. Persson Theoretical state-of-the art in adsorbate motions and reactions induced by inelastic tunneling current with STM Surf. Sci. 566 2004 1 12
107. S.K. Sarkar, and J.P. Mittal Laser selective chemistry Lasers Mater. Sci. 301 1999 1 46
108. F.F. Crim Bond-selected chemistry: Vibrational state control of photodissociation and bimolecular reaction J. Phys. Chem. 100 1996 12725 12734
109. F.F. Crim Vibrational state control of bimolecular reactions: discovering and directing the chemistry Acc. Chem. Res. 32 1999 877 884
110. S.W. Hla, L. Bartels, G. Meyer, and K.H. Rieder Inducing all steps of a chemical reaction with the scanning tunneling microscope tip: towards single molecule engineering Phys. Rev. Lett. 85 2000 2777 2780
111. B.C. Stipe, M.A. Rezaei, W. Ho, S. Gao, M. Persson, and B.I. Lundqvist Single-molecule dissociation by tunneling electrons Phys. Rev. Lett. 78 1997 4410 4413
112. Y. Kim, T. Komeda, and M. Kawai Single-molecule surface reaction by tunneling electrons Surf. Sci. 502-503 2002 7 11