Activation of nitriles by metal ligand cooperation. reversible formation of ketimido- and enamido-rhenium PNP pincer complexes and relevance to catalytic design

Journal of the American Chemical Society

Volumn 135, Issue 45, 2013, Pages 17004-17018

  Vogt, Matthias ^a   Nerush, Alexander ^a   Iron, Mark A ^a   Leitus, Gregory ^a   Diskin Posner, Yael ^a   Shimon, Linda J W ^a   Ben David, Yehoshoa ^a   Milstein, David ^a  

^a WEIZMANN INSTITUTE OF SCIENCE   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

COMPUTATIONAL STUDIES; METHYLENE GROUPS; MICHAEL ADDITIONS; PINCER COMPLEXES; REVERSIBLE BINDING; REVERSIBLE FORMATION; TEMPERATURE DEPENDENT; UNSATURATED ESTERS;

ADDITION REACTIONS; ALKYLATION; AROMATIC COMPOUNDS; CYANIDES;

RHENIUM COMPOUNDS;

BENZONITRILE; BENZYL CYANIDE DERIVATIVE; CARBENE; COORDINATION COMPOUND; LIGAND; METAL COMPLEX; NITRILE; PROTON; RHENIUM;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; COVALENT BOND; DENSITY FUNCTIONAL THEORY; ELECTRON; ENERGY; FLUORINE NUCLEAR MAGNETIC RESONANCE; METHYLATION; MICHAEL ADDITION; NUCLEAR OVERHAUSER EFFECT; NUCLEOPHILICITY; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; POLYMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; TEMPERATURE DEPENDENCE; X RAY DIFFRACTION;

EID: 84887763610     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja4071859     Document Type: Article

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