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Volumn 30, Issue 10, 2011, Pages 2721-2729

A dearomatized anionic PNP pincer rhodium complex: C-H and H-H bond activation by metal-ligand cooperation and inhibition by dinitrogen

Author keywords

[No Author keywords available]

Indexed keywords

C-H ACTIVATION; COMPLEX 1; DFT CALCULATION; DINITROGEN; H-H BOND ACTIVATION; METAL CENTERS; OXIDATIVE ADDITIONS; PINCER LIGANDS; PROTIC ENVIRONMENT; RHODIUM COMPLEXES; SPECTROSCOPIC CHARACTERIZATION;

EID: 79956092608     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om200104b     Document Type: Article
Times cited : (62)

References (68)
  • 13
    • 78049313129 scopus 로고    scopus 로고
    • For a review on catalytic reactions of alcohols catalyzed by PNN- and PNP-Ru pincer complexes, based on metal-ligand cooperation, see
    • For a review on catalytic reactions of alcohols catalyzed by PNN- and PNP-Ru pincer complexes, based on metal-ligand cooperation, see: Milstein, D. Top. Catal. 2010, 53, 915
    • (2010) Top. Catal. , vol.53 , pp. 915
    • Milstein, D.1
  • 42
    • 79956155944 scopus 로고    scopus 로고
    • 3a has been prepared previously by reaction of (PNP)Rh(OTf) with diphenylzinc, as described in ref 10
    • 3a has been prepared previously by reaction of (PNP)Rh(OTf) with diphenylzinc, as described in ref 10.
  • 45
    • 79956119730 scopus 로고    scopus 로고
    • note
    • 2 at -35 °C under dry argon resulted in the formation of a mixture of products.
  • 46
    • 0001346445 scopus 로고    scopus 로고
    • I fragment, probably as a result of steric hindrance; see
    • I fragment, probably as a result of steric hindrance; see: Vigalok, A.; Ben-David, Y.; Milstein, D. Organometallics 1996, 15, 1839
    • (1996) Organometallics , vol.15 , pp. 1839
    • Vigalok, A.1    Ben-David, Y.2    Milstein, D.3
  • 49
    • 79956075054 scopus 로고    scopus 로고
    • For preparation and characterization of complex 9 see ref 11b
    • For preparation and characterization of complex 9 see ref 11b.
  • 54
    • 79956118570 scopus 로고    scopus 로고
    • Complex 1 was also formed in the reaction as a byproduct, apparently as a result of reprotonation of 2 with adventitious water
    • Complex 1 was also formed in the reaction as a byproduct, apparently as a result of reprotonation of 2 with adventitious water.
  • 63
    • 0000766887 scopus 로고    scopus 로고
    • Grotendorst, J., Ed.; John von Neumann Institute for Computing: Jülich, Germany
    • Dolg, M. In Modern Methods and Algorithms of Quantum Chemistry; Grotendorst, J., Ed.; John von Neumann Institute for Computing: Jülich, Germany, 2000; Vol. 3, pp 507-540.
    • (2000) Modern Methods and Algorithms of Quantum Chemistry , vol.3 , pp. 507-540
    • Dolg, M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.