The "catalytic nitrosyl effect": NO bending boosting the efficiency of rhenium based alkene hydrogenations

Journal of the American Chemical Society

Volumn 135, Issue 10, 2013, Pages 4088-4102

  Jiang, Yanfeng ^a   Schirmer, Birgitta ^b   Blacque, Olivier ^a   Fox, Thomas ^a   Grimme, Stefan ^c   Berke, Heinz ^a  

^a UNIVERSITY OF ZURICH   (Switzerland)

^b UNIVERSITY OF MÜNSTER   (Germany)

^c UNIVERSITY OF BONN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE HYDROGENATION; HETEROLYTIC CLEAVAGE; HYDROGENATION ACTIVITY; HYDROGENATION CYCLE; INVERSE KINETIC ISOTOPE EFFECTS; MECHANISTIC STUDIES; PHOSPHINE LIGANDS; REDUCTIVE ELIMINATION;

DENSITY FUNCTIONAL THEORY; HYDROCARBONS; HYDROGENATION; ISOTOPES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOSPHORUS COMPOUNDS; RHENIUM;

CATALYST ACTIVITY;

ALKENE; HYDROGEN; ISOTOPE; PHOSPHONIUM DERIVATIVE; RHENIUM;

ARTICLE; CATALYSIS; DIFFUSION TENSOR IMAGING; HYDROGENATION; ISOMERIZATION; NITROSYLATION; NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT;

ALKANES; ALKENES; CATALYSIS; HYDROGENATION; MODELS, MOLECULAR; MOLECULAR STRUCTURE; NITRIC OXIDE; NITROSO COMPOUNDS; ORGANOMETALLIC COMPOUNDS; QUANTUM THEORY; RHENIUM;

EID: 84874984333     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja400135d     Document Type: Article

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