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Volumn 132, Issue 42, 2010, Pages 14763-14765

"Long-range" metel-ligand cooperation in h2 activation and ammonia-promoted hydride transfer with a ruthenium-acridine pincer complex

Author keywords

[No Author keywords available]

Indexed keywords

CLOSE PROXIMITY; DEAROMATIZATION; DFT CALCULATION; DIHYDRIDES; HYDRIDE LIGANDS; HYDRIDE TRANSFERS; INTERMEDIATE BEARING; METAL CENTERS; PINCER COMPLEXES; PINCER LIGANDS;

EID: 78649521145     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja107770y     Document Type: Article
Times cited : (120)

References (33)
  • 28
    • 0027953153 scopus 로고
    • 2 splitting over the methylacridinium salt was reported in modeling studies of hydrogenase enzyme activity using Cp*(dppm)RuH. Tetramethylpiperidine was employed as the hydride acceptor. See: Hembre, R. T.; McQueen, S. J. Am. Chem. Soc. 1994, 116, 2141.
    • (1994) J. Am. Chem. Soc. , vol.116 , pp. 2141
    • Hembre, R.T.1    McQueen, S.2
  • 29
    • 78649756187 scopus 로고    scopus 로고
    • H/D exchange into the alkylphosphine groups was also observed. See the Supporting Information
    • H/D exchange into the alkylphosphine groups was also observed. See the Supporting Information.
  • 32
    • 78649726599 scopus 로고    scopus 로고
    • note
    • All of the calculations were carried out using DFT at the PCM(toluene)M06+d/SDB-cc-pVDZ//M06/SDD(d) level (see the Supporting Information for details and references). All energies are reported in kcal/mol and, unless stated otherwise, they are relative to A. A (') is used to denote model complexes having Me-P in lieu of i-Pr-P.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.