The first f-element ketimido complex: Synthesis and characterization of (C5Me5)2U(-N=CPh2)2

Organometallics

Volumn 21, Issue 15, 2002, Pages 3073-3075

  Kiplinger, Jaqueline L ^a   Morris, David E ^a   Scott, Brian L ^a   Burns, Carol J ^a  

^a LOS ALAMOS NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL STABILITY;

CATALYSIS; CHEMICAL BONDS; COMPLEXATION; SYNTHESIS (CHEMICAL);

ORGANOMETALLICS;

EID: 0037812660     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om020381k     Document Type: Article

References (23)

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11. (c) Warner, B. P.; Scott, B. L.; Burns, C. J. Angew. Chem., Int. Ed. 1998, 37, 959-960.
12. (d) Duval, P. B.; Burns, C. J.; Clark, D. L.; Morris, D. E.; Scott, B. L.; Thompson, J. D.; Werkema, E. L.; Jia, L.; Andersen, R. A. Angew. Chem., Int. Ed. 2001, 40, 3358-3361.
13. (a) Evans, W. J.; Meadows, J. H.; Hunter, W. E., Atwood, J. L. J. Am. Chem. Soc. 1984, 106, 1291-1300.
14. (b) Erker, G.; Frömberg, W.; Krüger, C.; Raabe, E. J. Am. Chem. Soc. 1988, 110, 2400-2405.
15. (c) Zippel, T.; Arndt, P.; Ohff, A.; Spannenberg, A.; Kempe, R.; Rosenthal, U. Organometallics 1998, 17, 4429-4437 and references therein.
16. 2U (mol wt 868.91): C, 63.58; H, 5.80; N, 3.23. Found: C, 63.51; H, 5.85; N, 3.27.
17. 3, T = 203 K, R(I > 2σ) = 0.0376, and GOF = 1.242.
18. Peters, R. G.; Scott, B. L.; Burns, C. J. Unpublished results.
19. Arney, D. S. J.; Burns, C. J.; Smith, D. C. J. Am. Chem. Soc. 1992, 114, 10068-10069.
20. Allen, F. H.; Kennard, P.; Watson, D. G.; Brammer, L.; Orpen, A. G.; Taylor, R. J. Chem. Soc., Perkin Trana. 2 1987, S1-S19.
21. 2 core.
22. Morris, D. E.; Kiplinger, J. L.; Burns, C. J. Manuscript in preparation.
23. Carnall, W. T.; Crosswhite, H. M. Optical Spectra and Electronic Structure of Actiniae Ions in Compounds and in Solution; Argonne National Laboratory Report ANL-84-90; August 1985.