Consecutive thermal H2 and light-induced O2 evolution from water promoted by a metal complex

Science

Volumn 324, Issue 5923, 2009, Pages 74-77

  Kohl, Stephan W ^a   Weiner, Lev ^a   Schwartsburd, Leonid ^a   Konstantinovski, Leonid ^a   Shimon, Linda J W ^a   David, Yehoshoa Ben ^a   Iron, Mark A ^a   Milstein, David ^a  

^a WEIZMANN INSTITUTE OF SCIENCE   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN; HYDROGEN PEROXIDE; METAL COMPLEX; OXYGEN; RUTHENIUM; WATER;

CATALYST; CHEMICAL BONDING; HYDROGEN; HYDROGEN PEROXIDE; ISOTOPIC ANALYSIS; MOLECULAR ANALYSIS; OXYGEN; RENEWABLE RESOURCE; RUTHENIUM; STOICHIOMETRY;

ARTICLE; CATALYST; CHEMICAL REACTION; CHEMICAL STRUCTURE; IRRADIATION; ISOTOPE LABELING; PHOTOLYSIS; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; STOICHIOMETRY; SUNLIGHT; SYNTHESIS;

EID: 64249155542     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1168600     Document Type: Article

References (36)

1. N. S. Lewis, D. G. Nocera, Proc. Natl. Acad. Sci. U.S.A. 103, 15729 (2006).
2. V. Balzani, A. Credi, M. Venturi, ChemSusChem 1, 26 (2008).
3. R. A. Binstead, C. W. Chronister, J. Ni, C. W. Hartshorn, T. J. Meyer, J. Am. Chem. Soc. 122, 8464 (2000).
4. J. H. Alstrum-Acevedo, M. K. Brennaman, T. J. Meyer, Inorg. Chem. 44, 6802 (2005).
5. T. A. Betley, Q. Wu, T. Van Voorhis, D. G. Nocera, Inorg. Chem. 47, 1849 (2008).
6. J. K. Hurst, Coord. Chem. Rev. 249, 313 (2005).
7. M. Yagi, M. Kaneko, Chem. Rev. 101, 21 (2001).
8. W. Ruttinger, G. C. Dismukes, Chem. Rev. 97, 1 (1997).
9. I. Romero et al., Inorg. Chem. 47, 1824 (2008).
10. Z. Deng, H.-W. Tseng, R. Zong, D. Wang, R. Thummel, Inorg. Chem. 47, 1835 (2008).
11. J. K. Hurst, J. L. Cape, A. E. Clark, S. Das, C. Qin, Inorg. Chem. 47, 1753 (2008).
12. X. Yang, M.-H. Baik, J. Am. Chem. Soc. 128, 7476 (2006).
13. J. T. Muckerman, D. E. Polyansky, T. Wada, K. Tanaka, E. Fujita, Inorg. Chem. 47, 1787 (2008).
14. N. D. McDaniel, F. J. Coughlin, L. L. Tinker, S. Bernhard, J. Am. Chem. Soc. 130, 210 (2008); and references therein.
15. Y. V. Geletii et al., Angew. Chem. Int. Ed. 47, 3896 (2008); and references therein.
16. J. Limburg et al., Science 283, 1524 (1999).
17. S. Chakraborty, T. J. Wadas, H. Hester, R. Schmehl, R. Eisenberg, Inorg. Chem. 44, 6865 (2005).
18. J. Zhang, G. Leitus, Y. Ben-David, D. Milstein, J. Am. Chem. Soc. 127, 10840 (2005).
19. C. Gunanathan, Y. Ben-David, D. Milstein, Science 317, 790 (2007).
20. Experimental details are available as supporting material on Science Online.
21. † = 3.6 kcal/mol. According to this DFT calculation, the D atom would selectively transfer to the same side of the double bond as the hydroxo ligand, but we have not yet demonstrated this experimentally.
22. P. E. M. Siegbahn, M. R. A. Blomberg, M. Svenson, J. Phys. Chem. 97, 2564 (1993).
23. D. Milstein, J. C. Calabrese, I. D. Williams, J. Am. Chem. Soc. 108, 6387 (1986).
24. O. Blum, D. Milstein, J. Am. Chem. Soc. 117, 4582 (1995).
25. 2O (rather then 2) avoided the formation of impurities.
26. A. W. Kaplan, R. G. Bergman, Organometallics 17, 5072 (1998).
27. We used a filter made of polymethylmethacrylate (perspex, thickness = 1 cm) during the irradiation. This material absorbs UV light at wavelengths shorter than λ = 320 nm. Irradiation without perspex gave more by-products, and dioxygen was formed in only 19% yield.
28. (IV)(Cl)(OH) complex was suggested (29).
29. Y. Nakabayashi et al., Chem. Eur. J. 13, 3980 (2007).
30. S. Kato, T. Ueno, S. Fukuzumi, Y. Watanabe, J. Biol. Chem. 279, 52376 (2004).
31. C. Walling, Acc. Chem. Res. 8, 125 (1975).
32. M. A. Grela, M. E. J. Coronel, A. J. Colussi, J. Phys. Chem. 100, 16940 (1996).
33. J. von Sonntag, E. Mvula, K. Hildenbrand, C. von Sonntag, Chem. Eur. J. 10, 440 (2004).
34. For such a proton migration process with a PNP-Ir(I) complex, see (35).
35. E. Ben-Ari, G. Leitus, L. J. W. Shimon, D. Milstein, J. Am. Chem. Soc. 128, 15390 (2006).
36. 2O are available free of charge from the Cambridge Crystallographic Data Centre under identification number CCDC-681749.