A mononuclear non-heme high-spin iron(III)-hydroperoxo complex as an active oxidant in sulfoxidation reactions

Journal of the American Chemical Society

Volumn 135, Issue 24, 2013, Pages 8838-8841

  Kim, Yun Mi ^a   Cho, Kyung Bin ^a   Cho, Jaeheung ^a,c   Wang, Binju ^b   Li, Chunsen ^b   Shaik, Sason ^b   Nam, Wonwoo ^a  

^a Ewha Womans University   (South Korea)

^b HEBREW UNIVERSITY OF JERUSALEM   (Israel)

^c Daegu Gyeongbuk Institute of Science and Technology   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

BOND CLEAVAGES; DFT CALCULATION; EXPERIMENTAL EVIDENCE; HYDROPEROXO COMPLEX; NUMBER OF ELECTRONS; REACTION PATHWAYS; SPIN STATE; SULFOXIDATION;

CHEMISTRY; SYNTHESIS (CHEMICAL);

DENSITY FUNCTIONAL THEORY;

CHEMICAL COMPOUND; IRON(III) HYDROPEROXO COMPLEX; UNCLASSIFIED DRUG;

ARTICLE; COVALENT BOND; DENSITY FUNCTIONAL THEORY; ELECTRON; ELECTRON SPIN RESONANCE; SULFOXIDATION;

FERRIC COMPOUNDS; HETEROCYCLIC COMPOUNDS; MODELS, MOLECULAR; OXIDANTS; OXIDATION-REDUCTION; PEROXIDES; SULFIDES;

EID: 84879366051     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja404152q     Document Type: Article

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