Mechanism and selectivity of rhodium-catalyzed 1:2 coupling of aldehydes and allenes

Journal of the American Chemical Society

Volumn 135, Issue 20, 2013, Pages 7647-7659

  Huang, Genping ^a   Kalek, Marcin ^a   Himo, Fahmi ^a  

^a STOCKHOLM UNIVERSITY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

1 ,5-CYCLOOCTADIENE; CATALYST PRECURSORS; DENSITY FUNCTIONAL THEORY CALCULATIONS; OXIDATIVE COUPLINGS; PRODUCT DISTRIBUTIONS; RATE DETERMINING STEP; REACTION PATHWAYS; RHODIUM-CATALYZED;

ALDEHYDES; CATALYSIS; DENSITY FUNCTIONAL THEORY; HYDROCARBONS; REACTION INTERMEDIATES; RHODIUM; RHODIUM COMPOUNDS;

CATALYST SELECTIVITY;

ALDEHYDE DERIVATIVE; ALLENE DERIVATIVE; RHODIUM;

ALLYLATION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; COMPLEX FORMATION; DENSITY FUNCTIONAL THEORY; MOLECULAR MECHANICS; OXIDATION; REDUCTION;

ALDEHYDES; ALKADIENES; CATALYSIS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; QUANTUM THEORY; RHODIUM;

EID: 84878261653     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja4014166     Document Type: Article

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