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(a) Hong, Y.-T.; Barchuk, A.; Krische, M. J. Branch-Selective Intermolecular Hydroacylation: Hydrogen-Mediated Coupling of Anhydrides to Styrenes and Activated Olefins. Angew. Chem., Int. Ed. 2006, 128, 6885.
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See also
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(b) See also, Kokube, K.; Miura, M.; Nomura, M. Rhodium-Catalyzed Reaction of Benzoic Anhydride with Styrene under Molecular Hydrogen. Organometallics 1995, 14, 4521.
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To suppress decarbonylation in intermolecular rhodium catalyzed hydroacylation, aldehyde donors that possess an adjacent site of coordination are required (for example, salicyladehydes and β-sulfidoaldehydes). Alternatively, conventional aldehyde donors may be converted to the corresponding (N-2-pyridyl)aldimines, which are then used as aldehyde equivalents: (a) Vora, K. P.; Lochow, C. F.; Miller, R. G. Rhodium Catalyzed Hydrogenation of Ethylene with 4-Pentenals. Reactions of 4-Hexenal-1-d. J. Organomet. Chem. 1980, 192, 257.
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To suppress decarbonylation in intermolecular rhodium catalyzed hydroacylation, aldehyde donors that possess an adjacent site of coordination are required (for example, salicyladehydes and β-sulfidoaldehydes). Alternatively, conventional aldehyde donors may be converted to the corresponding (N-2-pyridyl)aldimines, which are then used as aldehyde equivalents: (a) Vora, K. P.; Lochow, C. F.; Miller, R. G. Rhodium Catalyzed Hydrogenation of Ethylene with 4-Pentenals. Reactions of 4-Hexenal-1-d. J. Organomet. Chem. 1980, 192, 257.
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Rhodium Zeolites as Bifunctional Catalysts for the Synthesis of 2-Methylhexan-3-one and Heptan-4-one from Propylene. Carbon Monoxide, and Hydrogen
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Transition-Metal-Catalyzed C-C Bond Formation via C-H Activation. Intermolecular Hydroacylation: The Addition of Aldehydes to Alkenes
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(c) Marder, T. B.; Roe, D. C.; Milstein, D. Transition-Metal-Catalyzed C-C Bond Formation via C-H Activation. Intermolecular Hydroacylation: The Addition of Aldehydes to Alkenes. Organometallics 1988, 7, 1451.
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Solvent Free Chelation-Assisted Intermolecular Hydroacylation: Effect of Microwave Irradiation in the Synthesis of Ketone from Aldehyde and 1-Alkene by Rh(I) Complex
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(f) Jun, C.-H.; Chung, J.-W.; Lee, D.-Y.; Loupy, A.; Chatti, S. Solvent Free Chelation-Assisted Intermolecular Hydroacylation: Effect of Microwave Irradiation in the Synthesis of Ketone from Aldehyde and 1-Alkene by Rh(I) Complex. Tetrahedron Lett. 2001, 42, 4803.
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Intermolecular Hydroacylation of Acrylate Esters: A New Route to 1,4-Diacrbonyls
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Oxidative Addition of Carboxylic Acid Anhydrides to Rhodium(I) Phosphine Complexes To Produce Novel Rhodium(III) Acyl Derivatives
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