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0042773345
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note
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The retention of absolute configuration in the rhodium-catalyzed allylic amination was assigned by the comparison of (R)-2f prepared from (A)-1f (Scheme 1) with (S)-2f prepared via Mitsunobu inversion of the allylic alcohol (R)-1f́ with N-4-methoxybenzenesulfonyl toluidine. equation presented
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31
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0041771438
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note
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7c
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32
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0043274640
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note
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Although β-branching is tolerated, α-branching leads to significantly reduced secondary selectivity. The allylic animation of the isopropyl derived allylic carbonate I furnished the allylic animation products II/III as a 1:2 mixture favoring the primary product III. equation presented
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33
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0000458209
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