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Volumn 16, Issue 9, 2003, Pages 567-578

Recent Developments in Rhodium-Catalyzed Allylic Substitution and Carbocyclization Reactions

(2)  Evans, P Andrew a   Leahy, David K a  

a NONE

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; RHODIUM DERIVATIVE;

EID: 0242720245     PISSN: 14319268     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Review
Times cited : (14)

References (52)
  • 13
    • 0000969879 scopus 로고    scopus 로고
    • Wiley: New York, ch. 4
    • For book chapters on metal-catalyzed allylic substitution, see: (a) Tsuji, J. In Palladium Reagents and Catalysts, Wiley: New York, 1996, ch. 4, pp. 290-404;
    • (1996) Palladium Reagents and Catalysts , pp. 290-404
    • Tsuji, J.1
  • 15
    • 0027380506 scopus 로고
    • For lead references on other transition metal-catalyzed allylic alkylation reactions, see: (a) Co: Bhatia, B., Reddy, M.M., Iqbal, J. Tetrahedron Lett. 1993, 34, 6301;
    • (1993) Tetrahedron Lett. , vol.34 , pp. 6301
    • Bhatia, B.1    Reddy, M.M.2    Iqbal, J.3
  • 32
    • 0000849837 scopus 로고    scopus 로고
    • For related examples of rhodium-catalyzed allylic substitution reactions, see: (a) Takeuchi, R., Kitamura, N. New. J. Chem. 1998, 659;
    • (1998) New. J. Chem. , pp. 659
    • Takeuchi, R.1    Kitamura, N.2
  • 33
    • 0012543140 scopus 로고    scopus 로고
    • pertinent references therein
    • (b) Fagnou, K., Lautens, M. Org. Lett. 2000, 2, 2319 and pertinent references therein.
    • (2000) Org. Lett. , vol.2 , pp. 2319
    • Fagnou, K.1    Lautens, M.2
  • 34
    • 0001528563 scopus 로고
    • Abel, E.W., Stone, F.G.A., Wilkinson, G., eds., Pergamon Press: New York, ch. 2
    • Enyl complexes are, by definition, those that have a discrete σ- and π-metal carbon component within a single ligand. Sharp, P.R. In Comprehensive Organometallic Chemistry II, Abel, E.W., Stone, F.G.A., Wilkinson, G., eds., Pergamon Press: New York, 1995, ch. 2, p. 272.
    • (1995) Comprehensive Organometallic Chemistry II , pp. 272
    • Sharp, P.R.1
  • 36
    • 0242558426 scopus 로고    scopus 로고
    • note
    • The term conservation of enantiomeric excess {cee = (product ee/starting material ee) × 100} provides a convenient method of describing the enantiospecificity of the reaction.
  • 39
    • 0344006321 scopus 로고    scopus 로고
    • pertinent references cited therein
    • For a recent review on ring-closing metathesis, see: Fürstner, A. Angew. Chem. Int. Ed. 2000, 39, 3012 and pertinent references cited therein.
    • (2000) Angew. Chem. Int. Ed. , vol.39 , pp. 3012
    • Fürstner, A.1
  • 42
  • 45
    • 0000330557 scopus 로고    scopus 로고
    • For recent reviews on metal-mediated cyclooctanoid construction, see: (a) Mehta, G., Singh, V. Chem. Rev. 1999, 99, 881;
    • (1999) Chem. Rev. , vol.99 , pp. 881
    • Mehta, G.1    Singh, V.2
  • 46
    • 0034246704 scopus 로고    scopus 로고
    • (b) Yet, L. Chem. Rev. 2000, 100, 2963.
    • (2000) Chem. Rev. , vol.100 , pp. 2963
    • Yet, L.1
  • 49
    • 0034601016 scopus 로고    scopus 로고
    • The rhodium-catalyzed cycloisomerization of 1,3-butadiene is known to favor oligomerization rather than the formation of cyclooctadiene, see: Bosch, M., Brookhart, M.S., Ilg, K., Werner, H. Angew Chem. Int. Ed. 2000, 39, 2304.
    • (2000) Angew Chem. Int. Ed. , vol.39 , pp. 2304
    • Bosch, M.1    Brookhart, M.S.2    Ilg, K.3    Werner, H.4
  • 50
    • 0242643109 scopus 로고    scopus 로고
    • note
    • The stereochemistry of the major diastereoisomer was reassigned based on a recent X-ray crystal structure. The rather unusual eight-membered ring conformation forces the protons pseudo-equational explaining the observed NOE enhancement (5.2%), despite their trans-relationship.
  • 51
    • 0034686072 scopus 로고    scopus 로고
    • For a recent review on the Pauson-Khand reaction, see: Brummond, K.M., Kent, J.L. Tetrahedron 2000, 56, 3263.
    • (2000) Tetrahedron , vol.56 , pp. 3263
    • Brummond, K.M.1    Kent, J.L.2
  • 52


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.