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Volumn 42, Issue 23, 2013, Pages 8276-8287

On the structural diversity of [K(18-crown-6)EPh3] complexes (E = C, Si, Ge, Sn, Pb): Synthesis, crystal structures and NOESY NMR study

Author keywords

[No Author keywords available]

Indexed keywords

CONTACT ION PAIRS; COORDINATION PROPERTIES; GROUP 14 ELEMENT; HETEROLYTIC CLEAVAGE; SOLID-STATE STRUCTURES; SPECTROSCOPIC STUDIES; STRUCTURAL DIVERSITY; X RAY CRYSTAL STRUCTURES;

EID: 84878069504     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/c3dt50523e     Document Type: Article
Times cited : (30)

References (102)
  • 1
    • 84878086286 scopus 로고
    • G. E. Coats, B. J. Aylett, M. L. H. Green, D. M. Mingos and K. Wade, part 2, 1-386
    • B. J. Aylett, in Organometallic Compounds, ed., G. E. Coats, B. J. Aylett, M. L. H. Green, D. M. P. Mingos, and, K. Wade, 1979, vol. 1, part 2, pp. 1-386
    • (1979) Organometallic Compounds , vol.1
    • Aylett, B.J.1
  • 23
    • 0000863882 scopus 로고
    • Angew. Chem., Int. Ed. Engl. 1991 30 1459 1460
    • D. Reed D. Stalke D. S. Wright Angew. Chem. 1991 103 1539 1540 Angew. Chem., Int. Ed. Engl. 1991 30 1459 1460
    • (1991) Angew. Chem. , vol.103 , pp. 1539-1540
    • Reed, D.1    Stalke, D.2    Wright, D.S.3
  • 48
    • 79954603330 scopus 로고    scopus 로고
    • Angew. Chem., Int. Ed. 2010 47 8513 8515
    • D. J. Vyas M. Oestreich Angew. Chem. 2010 122 8692 8694 Angew. Chem., Int. Ed. 2010 47 8513 8515
    • (2010) Angew. Chem. , vol.122 , pp. 8692-8694
    • Vyas, D.J.1    Oestreich, M.2
  • 63
    • 84878100653 scopus 로고    scopus 로고
    • 2B-SnR ′ 3 have been described but were not explored in great detail. However, they appear to be of low stability and were not investigated within this work. Lead boron compounds bearing oxygen substituents at the boron moiety have not been described in detail. 12,13,15c
    • S. Westcott, J. Webb, D. I. McIsaac and C. M. Vogels, WO 2006/089402 A1, 2006
    • (2006)
    • Westcott, S.1    Webb, J.2    McIsaac, D.I.3    Vogels, C.M.4
  • 68
    • 36849090666 scopus 로고    scopus 로고
    • Attempts to perform X-ray powder diffraction measurements on the black material separated from solutions of 4c were unsuccessful due to its fine and adhesive nature. However, an X-ray powder diffraction analysis of material obtained by heating neat 4c to 114-116 °C revealed that it consists indeed of elemental lead and additional, unidentified crystalline material. See the ESI for details
    • L. Weber Coord. Chem. Rev. 2008 252 1 31
    • (2008) Coord. Chem. Rev. , vol.252 , pp. 1-31
    • Weber, L.1
  • 69
    • 80054988285 scopus 로고    scopus 로고
    • Ph distances appears, due to the very unsymmetrical nature of this interaction, more useful than the use of K-centroid distances See for example
    • C. Kleeberg Z. Anorg. Allg. Chem. 2011 637 1790 1794
    • (2011) Z. Anorg. Allg. Chem. , vol.637 , pp. 1790-1794
    • Kleeberg, C.1
  • 81
    • 20544433165 scopus 로고
    • See the ESI for details The stereochemistry of and the dynamic process present in propeller-shaped molecules have been studied extensively. Generally, various isomerisation processes involving the rotation about X-Ph bonds are feasible. However, a detailed analysis and estimation of the activation parameters of the dynamic processes present in 6a remains the subject of further studies. See for example
    • A. Bondi J. Phys. Chem. 1964 68 441 452
    • (1964) J. Phys. Chem. , vol.68 , pp. 441-452
    • Bondi, A.1
  • 102
    • 84878079815 scopus 로고    scopus 로고
    • Crystal Impact GbR, Bonn, Germany
    • K. Brandenburg, Diamond 3.2i, Crystal Impact GbR, Bonn, Germany, 1997
    • (1997) Diamond 3.2i
    • Brandenburg, K.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.