Boron-metal exchange reaction of silylboranes with organometallic reagents: A new route to arylsilyl anions

Chemistry Letters

Volumn , Issue 12, 2001, Pages 1216-1217

  Kawachi, Atsushi ^a   Minamimoto, Takashi ^a   Tamao, Kohei ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0035528503     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2001.1216     Document Type: Article

References (35)

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23. -3, 0.78 mL, 0.9 mmol) at -78 °C. The reaction mixture was stirred at the same temperature for 30 min to give 3a. To the solution of 3a was added trimethylchlorosilane (0.14 mL, 1.1 mmol) at -78 °C, and the reaction mixture was warmed to the ambient temperature. After usual workup, 4a was obtained in 87% yield after column chromatography on silica gel.
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