Trimesitylmethylphosphonium cation. Supramolecular stereocontrol and simple enantiomerization mechanism determination

Journal of Organic Chemistry

Volumn 71, Issue 19, 2006, Pages 7412-7416

  Laleu, Benoît ^a   Bernardinelli, Gérald ^a   Chauvin, Remi ^b   Lacour, Jérôme ^a  

^a UNIVERSITY OF GENEVA   (Switzerland)

^b LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

Author keywords

[No Author keywords available]

Indexed keywords

IONS; PHOSPHORUS COMPOUNDS; POSITIVE IONS; SOLUTIONS;

ENANTIOMERIZATION; ION PAIRING; TRIMESITYLMETHYLPHOSPHONIUM CATIONS;

SUPRAMOLECULAR CHEMISTRY;

PHOSPHONIUM DERIVATIVE;

ARTICLE; CHIRALITY; CONFORMATION; CRYSTAL STRUCTURE; DIASTEREOISOMER; ENANTIOMERIZATION; ENTROPY; ISOMERISM; ISOMERIZATION; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 33748991444     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo061097w     Document Type: Article

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91. exchange.
92. exchange is thus undefined.
93. enantio.
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95. exchange on the very same proton spectra as to minimize the temperature error which would have been, otherwise, not negligible.
96. exchange value is in perfect agreement with previous experiments (see ref 7).
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99. maj and min identify signals from the major and minor conformers, respectively.