Copper-catalyzed 1,2-addition of nucleophilic silicon to aldehydes: Mechanistic insight and catalytic systems

Chemistry - A European Journal

Volumn 17, Issue 48, 2011, Pages 13538-13543

  Kleeberg, Christian ^a   Feldmann, Evgenia ^a   Hartmann, Eduard ^b   Vyas, Devendra J ^b,c   Oestreich, Martin ^b  

^a TECHNICAL UNIVERSITY OF BRAUNSCHWEIG   (Germany)

^b UNIVERSITY OF MÜNSTER   (Germany)

^c NRW Graduate School of Chemistry   (Germany)

Author keywords

aldehydes; copper; nucleophilic addition; silicon; transmetalation; X ray diffraction

Indexed keywords

ALIPHATIC ALDEHYDES; ALKOXIDES; BORIC ACIDS; BROOK REARRANGEMENT; CATALYTIC CYCLES; CATALYTIC SYSTEM; COPPER-BASED; ELEVATED TEMPERATURE; EXCHANGE RATES; GOOD YIELD; MILD REACTION CONDITIONS; NUCLEOPHILIC ADDITIONS; PRIMARY REACTION; SPECTROSCOPIC MEASUREMENTS; TRANSMETALATION;

ADDITION REACTIONS; ALDEHYDES; COPPER; EXPERIMENTS; INORGANIC ACIDS; IODINE; LIGANDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; NUCLEOPHILES; SILICON; X RAY DIFFRACTION;

ORGANIC COMPOUNDS;

EID: 81755163145     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201102367     Document Type: Article

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