Anomalous reactivity of silylborane: Transition-metal-free boryl substitution of aryl, alkenyl, and alkyl halides with silylborane/alkoxy base systems

Journal of the American Chemical Society

Volumn 134, Issue 49, 2012, Pages 19997-20000

  Yamamoto, Eiji ^a   Izumi, Kiyotaka ^a   Horita, Yuko ^a   Ito, Hajime ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENYL; ALKYL HALIDES; ARYL BROMIDES; BASE SYSTEMS; BORYL COMPOUNDS; BORYLATION; HIGH YIELD; MECHANISTIC STUDIES; ORGANIC HALIDES; RADICAL-MEDIATED PROCESS;

FUNCTIONAL GROUPS;

TRANSITION METALS;

ALKENYL GROUP; ALKYL GROUP; BORANE DERIVATIVE; ORGANOHALOGEN DERIVATIVE; SILYLBORANE; TRANSITION ELEMENT; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL MODIFICATION; CONTROLLED STUDY; STEREOSPECIFICITY; SUBSTITUTION REACTION;

EID: 84870896468     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja309578k     Document Type: Article

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