Chiral fluorinated α-sulfonyl carbanions: Enantioselective synthesis and electrophilic capture, racemization dynamics, and structure

Chemistry - A European Journal

Volumn 19, Issue 12, 2013, Pages 3869-3897

  Hellmann, Gunther ^a,b   Hack, Achim ^a,c   Thiemermann, Eric ^a,d   Luche, Olaf ^a,e   Raabe, Gerhard ^a   Gais, Hans Joachim ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

^b DSM NUTRITIONAL PRODUCTS LTD   (Switzerland)

^c IMPAG AG   (Switzerland)

^d F HOFFMANN LA ROCHE LTD   (Switzerland)

^e LISI Automotive Knipping   (Germany)

Author keywords

ab initio calculations; carbanions; chirality; racemization; sulfone

Indexed keywords

AB INITIO CALCULATIONS; CARBANIONS; CONFIGURATIONAL STABILITY; CRYSTAL STRUCTURE ANALYSIS; ENANTIOSELECTIVE SYNTHESIS; RACEMIZATION; SULFONE; TETRAMETHYLETHYLENEDIAMINE;

AMIDES; CALCULATIONS; CHIRALITY; ENANTIOMERS; ENANTIOSELECTIVITY; IONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC SOLVENTS; SALTS; STABILIZATION; SULFUR DIOXIDE; SYNTHESIS (CHEMICAL);

LITHIUM;

EID: 84874976710     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201204014     Document Type: Article

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