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Volumn 18, Issue 33, 2012, Pages 10382-10392

Stereoselective preparation of (E)-configured 1,2-disubstituted propenes from two aldehydes by a two-carbon stitching strategy: Convergent synthesis of 18,21-diisopropyl-geldanamycin hydroquinone and its C7 epimer

(4) Hampel, Thomas a,c Neubauer, Thomas a Van Leeuwen, Thomas b Bach, Thorsten a

a TECHNICAL UNIVERSITY OF MUNICH (Germany)

b UNIVERSITY OF GRONINGEN (Netherlands)

c BOEHRINGER INGELHEIM PHARMA GMBH AND CO KG (Germany)

Author keywords

C C coupling; carbenoids; halogenation; natural products; synthetic methods

Indexed keywords

AMINO GROUP; BUILDING BLOCKES; C-C COUPLING; CARBENOIDS; CHIRAL POOL; CONVERGENCY; CONVERGENT SYNTHESIS; D-MANNITOL; DEPROTECTION; DIASTEREOSELECTIVE REDUCTION; DOUBLE BONDS; GELDANAMYCIN; MAGNESIUM CHLORIDES; METHYL ETHERS; NATURAL PRODUCTS; PROTECTING GROUP; STEREOGENIC CENTERS; STEREOSELECTIVE PREPARATION; SYNTHETIC METHODS; TITLE COMPOUNDS;

ALDEHYDES; CARBON; CHLORINE COMPOUNDS; ETHERS; HALOGENATION; KETONES; MAGNESIUM; PHENOLS; STEREOSELECTIVITY;

ORGANIC COMPOUNDS;

18,21 DIISOPROPYL GELDANAMYCIN HYDROQUINONE; 18,21-DIISOPROPYL-GELDANAMYCIN HYDROQUINONE; ALDEHYDE; ALKENE; HYDROQUINONE DERIVATIVE; MACROCYCLIC LACTAM; PROPYLENE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

ALDEHYDES; ALKENES; HYDROQUINONES; LACTAMS, MACROCYCLIC; MOLECULAR STRUCTURE; STEREOISOMERISM;

EID: 84864616669 PISSN: 09476539 EISSN: 15213765 Source Type: Journal
DOI: 10.1002/chem.201201600 Document Type: Article

Times cited : (18)

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