Biomimetic enantioselective total synthesis of (-)-siccanin via the Pd-catalyzed asymmetric allylic alkylation (AAA) and sequential radical cyclizations

Journal of the American Chemical Society

Volumn 126, Issue 39, 2004, Pages 12565-12579

  Trost, Barry M ^a   Shen, Hong C ^a   Surivet, Jean Philippe ^a  

^a STANFORD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYLATION; BIOMIMETIC MATERIALS; BIOSYNTHESIS; CATALYSIS; COMPLEXATION; PALLADIUM; SUBSTITUTION REACTIONS;

BIOMIMETIC ROUTES; ENANTIOSELECTIVITY; EPOXYOLEFINS; SEQUENTIAL RADICAL CYCLIZATION;

OLEFINS;

ALKENE; ALLYL COMPOUND; CARBONIC ACID DERIVATIVE; CHROMAN DERIVATIVE; DIMETHYL ETHER; EPOXIDE; NATURAL PRODUCT; PALLADIUM; PHENOL DERIVATIVE; RADICAL; SICCANIN; SICCANOCHROMENE A; SICCANOCHROMENE B; SICCANOCHROMENE C; SICCANOCHROMENE E; SICCANOCHROMENE F; TETRAHYDROFURAN; TITANIUM; UNCLASSIFIED DRUG;

ALKYLATION; ARTICLE; ASYMMETRIC ALLYLIC ALKYLATION; ASYMMETRIC CATALYSIS; BIOMIMETICS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLIZATION; ENANTIOSELECTIVITY; REACTION ANALYSIS; SUAREZ REACTION; SYNTHESIS;

ALKYLATION; ALLYL COMPOUNDS; ANTIFUNGAL AGENTS; BIOMIMETIC MATERIALS; CATALYSIS; CYCLIZATION; HELMINTHOSPORIUM; MODELS, MOLECULAR; PALLADIUM; STEREOISOMERISM; XANTHENES;

EID: 4644308019     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja048084p     Document Type: Article

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