Synthesis, characterization, and reactivity of Fe complexes containing cyclic diazadiphosphine ligands: The role of the pendant base in heterolytic cleavage of H 2

Journal of the American Chemical Society

Volumn 134, Issue 14, 2012, Pages 6257-6272

  Liu, Tianbiao ^a   Chen, Shentan ^a   O'Hagan, Molly J ^a   Rakowski Dubois, Mary ^a   Bullock, R Morris ^a   Dubois, Daniel L ^a  

^a PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE SITE; BOND FORMATION; C ATOMS; CHELATE RING; CO LIGANDS; COMPUTATIONAL STUDIES; DIHYDROGEN COMPLEXES; ELECTROCHEMICAL STUDIES; FE COMPLEXES; FE SITES; H/D EXCHANGE; HETEROLYTIC CLEAVAGE; HYDRIDE COMPLEXES; HYDROGENASES; IRON COMPLEX; PENDANT BASE; REPULSIVE INTERACTIONS; STRUCTURAL STUDIES; VAN DER WAALS RADIUS;

ATOMS; CHELATION; IRON COMPOUNDS; LIGANDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC COMPOUNDS; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION;

CHLORINE COMPOUNDS;

CYCLIC DIAZADIPHOSPHINE LIGAND; DEUTERIUM; IRON COMPLEX; LIGAND; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CONFORMATION; CONTROLLED STUDY; CRYSTAL STRUCTURE; ELECTROCHEMICAL ANALYSIS; HYDROGEN BOND; INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PHOTOLYSIS; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; SYNTHESIS; X RAY DIFFRACTION;

BENZENE; ELECTROCHEMISTRY; ELECTRONS; FERROUS COMPOUNDS; FLUORINE; HYDROGEN; HYDROGENASE; IRON; LIGANDS; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, CHEMICAL; MODELS, MOLECULAR; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; PHOSPHINES;

EID: 84859581029     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja211193j     Document Type: Article

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