Syntheses and X-ray crystal structures of five- and six-coordinated iron(I) and iron(II) complexes with the same (η5-C5Me5)Fe(dppe) framework

Organometallics

Volumn 15, Issue 1, 1996, Pages 10-12

  Hamon, Paul ^a   Toupet, Loïc ^a   Hamon, Jean René ^a   Lapinte, Claude ^a  

^a UNIVERSITÉ DE RENNES 1   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0002557601     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om950766l     Document Type: Article

References (39)

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15. 3 (5): C, 58.94; H, 6.41. Found: C, 58.97; H, 6.49.
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21. Details of the structure determinations are provided as Supporting Information.
22. max = 50°, scan ω/2θ = 1). All non-hydrogen atoms were found by direct methods with the SHELX-86 program. Hydrogen atoms were idealized, and the whole structure was refined.
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25. max = 50°, scan ω/2θ = 1). All non-hydrogen atoms were found by direct methods with the SHELX-86 program. Hydrogen atoms were idealized, and the whole structure was refined.
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27. 8
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29. Isostructural diamagnetic complexes of Ru were characterized in situ by NMR: (a) Kirchner, K.; Mauthner, K.; Mereiter, K.; Schmid, R. J. Chem. Soc., Chem. Commun. 1993, 892. (b) Joslin, F. L.; Pontier Johnson, M.; Mague, J. T.; Roundhill, D. M. Organometallics 1991, 10, 2781.
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36. The role of hydrogen bonding is important in stabilizing the solid-state structure of aquo transition metal complexes: (a) Stang, P. J.; Cao, D. H.; Poulter, G. T.; Arif, A. M. Organometallics 1995, 14, 1110. (b) Braga, D.; Grepioni, F. Acc. Chem. Res. 1994, 27, 51.
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39. 6] occurs at -1.65 V vs SCE. Hamon, J.-R.; Lapinte, C. Unpublished results.