Iron hydrogenase active site mimic holding a proton and a hydride

Chemical Communications

Volumn , Issue 5, 2006, Pages 520-522

  Schwartz, Lennart ^a,b   Eilers, Gerriet ^b   Eriksson, Lars ^a   Gogoll, Adolf ^b   Lomoth, Reiner ^b   Ott, Sascha ^b  

^a STOCKHOLM UNIVERSITY   (Sweden)

^b UPPSALA UNIVERSITY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGENASE; IRON; IRON HYDROGENASE; PROTON; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; ENZYME ACTIVE SITE; ENZYME MECHANISM; INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION ANALYSIS; STRUCTURE ANALYSIS;

EID: 33645453106     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b514280f     Document Type: Article

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24. + could be observed on the timescale of hours, it cannot readily be determined which mono-protonated species is the thermodynamically stable form
25. 2+ revealed the coupling of the hydride to both phosphorus centers
26. +/0