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Volumn 118, Issue 23, 1996, Pages 5396-5407

Dihydrogen with frequency of motion near the 1H Larmor frequency. Solid-state structures and solution NMR spectroscopy of osmium complexes trans-[Os(H··H)X(PPh2CH2CH 2PPh2)2]+ (X = Cl, Br)

Author keywords

[No Author keywords available]

Indexed keywords

METAL COMPLEX; OSMIUM DERIVATIVE;

EID: 0029904366     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9529044     Document Type: Article
Times cited : (216)

References (61)
  • 1
    • 85087194347 scopus 로고    scopus 로고
    • note
    • 4 unless specified otherwise.
  • 9
    • 85087193920 scopus 로고    scopus 로고
    • note
    • 2 ligand with J(H,D) < 25 Hz. See ref 10.
  • 17
    • 4243057456 scopus 로고
    • Ph.D. Thesis. University of Toronto
    • Maltby, P. A. Ph.D. Thesis. University of Toronto, 1993.
    • (1993)
    • Maltby, P.A.1
  • 19
    • 0004150157 scopus 로고    scopus 로고
    • Siemens Analytical X-ray Instruments Inc., Madison, WI
    • Sheldrick, G. M. SHELXTL-PC, Siemens Analytical X-ray Instruments Inc., Madison, WI.
    • SHELXTL-PC
    • Sheldrick, G.M.1
  • 22
    • 4243059712 scopus 로고    scopus 로고
    • Craven, B. M. Program EKRT, University of Pittsburgh, 1992
    • Craven, B. M. Program EKRT, University of Pittsburgh, 1992.
  • 23
    • 4243070971 scopus 로고    scopus 로고
    • note
    • The libration of the H2 ligand creates banana-shaped smears of nuclear density at the ends of the H-H vector. When this shape is modeled by a thermal ellipsoid, an artificially short d(HH) is obtained. In order to verify the correction, calculations were also performed using Maverick and Trueblood's THMA14 program which yielded a value of 1.24 Å. See ref 24.
  • 31
    • 85087190504 scopus 로고    scopus 로고
    • note
    • 2 ligand.
  • 41
    • 4243087347 scopus 로고    scopus 로고
    • Personal communication
    • Eisenstein, O. Personal communication.
    • Eisenstein, O.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.