Kinetics and mechanism of the proton transfer to Cp*Fe(dppe)H: Absence of a direct protonation at the metal site

Journal of the American Chemical Society

Volumn 125, Issue 36, 2003, Pages 11106-11115

  Belkova, Natalia V ^a   Revin, Pavel O ^a   Epstein, Lina M ^a   Vorontsov, Evgenii V ^a   Bakhmutov, Vladimir I ^a,c   Shubina, Elena S ^a   Collange, Edmond ^b   Poli, Rinaldo ^b  

^a A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

^b UNIVERSITÉ DE BOURGOGNE   (France)

^c TEXAS A AND M UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN BONDS; IONIC CONDUCTION; ISOMERIZATION; PROTONS; SPECTROSCOPIC ANALYSIS;

PROTON DONORS;

REACTION KINETICS;

2 FLUOROETHANOL; ALKANOL; HEXAFLUORO 2 PROPANOL; IRON COMPLEX; PROTON; TRIFLUOROACETIC ACID; TRIFLUOROETHANOL; UNCLASSIFIED DRUG;

ARTICLE; COMPLEX FORMATION; MOLECULAR DYNAMICS; MOLECULAR INTERACTION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTON TRANSPORT; TEMPERATURE DEPENDENCE; TRANSPORT KINETICS; ULTRAVIOLET SPECTROSCOPY;

EID: 0041732421     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0358450     Document Type: Article

References (51)

1. Peruzzini, M., Poli, R., Eds. Recent Advances in Hydride Chemistry; Elsevier: Amsterdam, 2001.
2. Kristjánsdóttir, S. S.; Norton, J. R. In Transition Metal Hydrides; Dedieu, A., Ed.; VCH: New York, 1992; pp 309-359.
3. Papish, E. T.; Rix, F. C.; Spetseris, N.; Norton, J. R.; Williams, R. D. J. Am. Chem. Soc. 2000, 122, 12235-12242.
4. Papish, E. T.; Magee, M. P.; Norton, J. R. In Recent Advances in Hydride Chemistry; Peruzzini, M., Poli, R., Eds.; Elsevier: Amsterdam, 2001; pp 39-74.
5. Parkin, G.; Bercaw, J. E. J. Chem. Soc., Chem. Commun. 1989, 255-257.
6. Chinn, M. S.; Heinekey, D. M. J. Am. Chem. Soc. 1990, 112, 5166-5175.
7. Jia, G.; Lough, A. J.; Morris, R. H. Organometallics 1992, 11, 161-171.
8. Hamon, P.; Toupet, L.; Hamon, J.-R.; Lapinte, C. Organometallics 1992, 11, 1429-1431.
9. Hamon, J. R.; Hamon, P.; Toupet, L.; Costuas, K.; Saillard, J. Y. C. R. Acad. Sci., Ser. Ilc: Chim. 2002, 5, 89-98.
10. Morris, R. H. In Recent Advances in Hydride Chemistry; Peruzzini, M., Poli, R., Eds.; Elsevier: Amsterdam, 2001; pp 1-38.
11. Epstein, L. M.; Belkova, N. V.; Shubina, E. S. In Recent Advances in Hydride Chemistry; Peruzzini, M., Poli, R., Eds.; Elsevier: Amsterdam, 2001; pp 391-418.
12. Epstein, L. M.; Shubina, E. S. Coord. Chem. Rev. 2002, 231, 165-181.
13. Shubina, E. S.; Belkova, N. V.; Epstein, L. M. J. Organomet. Chem. 1997, 536-537, 17-29.
14. Kazarian, S. G.; Hamley, P. A.; Poliakoff, M. Chem. Commun. 1992, 994-997.
15. Kazarian, S. G.; Hamley, P. A.; Poliakoff, M. J. Am. Chem. Soc. 1993, 115, 9069-9079.
16. Poliakoff, M.; Howdle, S. M.; Kazarian, S. G. Angew. Chem., Int. Ed. Engl. 1995, 34, 1275-1295.
17. Shubina, E. S.; Krylov, A. N.; Kreindlin, A. Z.; Rybinskaya, M. I.; Epstein, L. M. J. Mol. Struct. 1993, 301, 1-5.
18. Shubina, E. S.; Krylov, A. N.; Muratov, D. V.; Filchikov, A. A.; Epstein, L. M. Russ. Chem. Bull. 1993, 42, 1919-1920.
19. Epstein, L. M.; Krylov, A. N.; Shubina, E. S. J. Mol. Struct. 1994, 322, 345-352.
20. Shubina, E. S.; Krylov, A. N.; Belkova, N. V.; Epstein, L. M.; Borisov, A. P.; Mahaev, V. D. J. Organomet. Chem. 1995, 493, 275-277.
21. Albinati, A.; Bakhmutov, V. I.; Belkova, N. V.; Bianchini, C.; de los Rios, I.; Epstein, L.; Gutsul, E. I.; Marvelli, L.; Peruzzini, M.; Rossi, R.; Shubina, E. S.; Vorontsov, E. V.; Zanobini, F. Eur. J. Inorg. Chem. 2002, 1530-1539.
22. Hascall, T.; Baik, M. H.; Bridgewater, B. A.; Shin, J. H.; Churchill, D. G.; Friesner, R. A.; Parkin, G. Chem. Commun. 2002, 2644-2645.
23. Belkova, N. V.; Gutsul, E. I.; Epstein, L.; Shubina, E. S.; Bianchini, C.; Zanobini, F.; Peruzzini, M., unpublished observations.
24. Basallote, M. G.; Durán, J.; Fernández-Trujillo, M. J.; Máñez, M. A.; de la Torre, J. R. J. Chem. Soc., Dalton Trans. 1998, 745-750.
25. Basallote, M. G.; Durán, J.; Fernández-Trujillo, M. J.; Máñez, M. A. J. Chem. Soc., Dalton Trans. 1998, 2205-2210.
26. Basallote, M. G.; Durán, J.; Fernández-Trujillo, M. J.; Máñez, M. A. Inorg. Chem. 1999, 38, 5067-5071.
27. Basallote, M. G.; Durán, J.; Fernández-Trujillo, M. J.; Máñez, M. A. J. Organomet. Chem. 2000, 609, 29-35.
28. Basallote, M. G.; Durán, J.; Fernández-Trujillo, M. J.; Máñez, M. A. Organometallics 2000, 19, 695-698.
29. de los Ríos, I.; Jiménez-Tenorio, M.; Padilla, J.; Puerta, M. C.; Valerga, P. Organometallics 1996, 15, 4565-4574.
30. Roger, C.; Hamon, P.; Toupet, L.; Rabaâ, H.; Saillard, J.-Y.; Hamon, J.-R.; Lapinte, C, Organometallics 1991, 10, 1045-1054.
31. Binstead, R. A.; Jung, B.; Zuberbühler A. D. Specfit/32; 2000 Spectrum Software Associates: Chapel Hill, NC. 2000.
32. Jetz, W.; Graham, W. A. G. Inorg. Chem. 1971, 10, 1159-1165.
33. Paciello. R. A.; Manriquez, J. M.; Bercaw, J. E. Organometallics 1990, 9, 260-165.
34. Hamon, P.; Hamon, J.-R.; Lapinte, C. J. Chem. Soc., Chem. Commun. 1992, 1602-1603.
35. Jiménez-Tenorio, M.; Puerta, M. C.; Valerga, P. Organometallics 1994, 13, 3330-3337.
36. Tilset, M.; Fjeldahl, I.; Hamon, J. R.; Hamon, P.; Toupet, L.; Saillard, J. Y.; Costuas, K.; Haynes, A. J. Am. Chem. Soc. 2001, 123, 9984-10000.
37. Jia, G.; Ng, W. S.; Yao, J.; Lau, C.-P.; Chen, Y. Organomemllics 1996, 15, 5039-5045.
38. Poli, R. In Recent Advances in Hydride Chemistry; Poli, R., Peruzzini, M., Eds.; Elsevier Science: Amsterdam, 2001: pp 139-188.
39. Bender, B. R.; Kubas. G. J.; Jones, L. H.; Swanson, B. I.; Eckert, J.; Capps, K. B.; Hoff, C. D. J. Am. Chem. Soc. 1997, 119, 9179-9190.
40. Girling, R. B.; Grebenik, P.; Perutz, R. N. Inorg. Chem. 1986, 25, 31-36.
41. Abdur-Rashid, K.; Fong, T. P.; Greaves. B.; Gusev, D. G.; Hinman, J. G.; Landau, S. E.; Lough, A. J.; Morris, R. H. J. Am. Chem. Soc. 2000, 122, 9155-9171.
42. Lever, A. B. P. Inorganic Electronic Spectroscopy, 2nd ed.; Elsevier: Amsterdam, 1984.
43. An NMR investigation also confirmed the absence of any proton transfer at room temperature in the presence of 12 equiv of MFE.
44. logansen, A. V. Hydrogen Bond; Nauka: Moscow, 1981; p 134.
45. Iogansen, A. V. Theor. Exp. Khim, 1971, 7, 312-317.
46. Bakhmutov, V. I.; Bakhmutova, E. V.; Belkova, N. V.; Bianchini, C.; Epstein, L. M.; Masi, D.; Peruzzini. M.; Shubina, E. S.; Vorontsov, E. V.; Zanobini, F. Can. J. Chem. 2001, 79, 479-489.
47. 2.
48. 2-show an identical first spectrum (ca. 1 ms).
49. Scheiner, S. Hydrogen bonding: A Theoretical Perspective: Oxford University Press: New York. 1997.
50. Belkova, N. V.; Ionidis, A. V.; Epstein, L. M.; Shubina, E. S.; Gruendemann, S.; Golubev. N. S.; Limbach, H. H. Eur. J. Inorg. Chem. 2001, 1753-1761.
51. Belkova, N. V.; Besora, M.; Epstein, L. M.; Lledós. A.; Maseras, F.; Shubina, E. S. J. Am. Chem Soc. 2003, 125, 7715-7725.