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Volumn 43, Issue 8, 2004, Pages 1006-1009

A biomimetic pathway for hydrogen evolution from a model of the iron hydrogenase active site

Author keywords

Bioinorganic chemistry; Biomimetic catalysis; Electrochemistry; Hydrogen; Iron hydrogenase

Indexed keywords

CATALYSTS; HYDROGENATION; MATHEMATICAL MODELS;

EID: 4544329387     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200353190     Document Type: Article
Times cited : (261)

References (29)
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    • (2003) Angew. Chem. Int. Ed. , vol.42 , pp. 3285-3288
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    • J. D. Lawrence, H. Li, T. B. Rauchfuss, M. Benard, M.-M. Rohmer, Angew. Chem. 2001, 113, 1818-1821; Angew. Chem. Int. Ed. 2001, 40, 1768-1771.
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    • 4544256542 scopus 로고    scopus 로고
    • note
    • CCDC-222734 (1) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/ retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ ccdc.cam.ac.uk).
  • 22
    • 4544232667 scopus 로고    scopus 로고
    • note
    • 6] (where R = phenyl) did not result in protonation of the bridge nitrogen atom, as evidenced by unchanged UV/Vis, IR, and NMR spectra.
  • 23
    • 4544382788 scopus 로고    scopus 로고
    • note
    • Acid titrations, monitored by electrochemical, UV/Vis, and IR techniques indicate that a slight excess of acid is required for exhaustive protonation of 1 (see the inset in Figure 2).
  • 24
    • 4544380215 scopus 로고    scopus 로고
    • note
    • pk.
  • 25
    • 4544327547 scopus 로고    scopus 로고
    • note
    • +.
  • 27
    • 0035915325 scopus 로고    scopus 로고
    • 6] as a calibrating agent, which is reduced at -1.16 V versus Ag/AgCl (F. Gloaguen, J. D. Lawrence, M. Schmidt, S. R. Wilson, T. B. Rauchfuss, J. Am. Chem. Soc. 2001, 123, 12518-12527). With our reference system and under otherwise identical conditions, this complex is reduced at -1.67 V, which gives rise to a ΔE value of 0.51 V.
    • (2001) J. Am. Chem. Soc. , vol.123 , pp. 12518-12527
    • Gloaguen, V.1    Lawrence, J.D.2    Schmidt, M.3    Wilson, S.R.4    Rauchfuss, T.B.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.